Metal-catalysed C–H bond activation and borylation

R Bisht, C Haldar, MMM Hassan, ME Hoque… - Chemical Society …, 2022 - pubs.rsc.org
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Catalytic reactions within the cavity of coordination cages

Y Fang, JA Powell, E Li, Q Wang, Z Perry… - Chemical Society …, 2019 - pubs.rsc.org
Natural enzymes catalyze reactions in their substrate-binding cavities, exhibiting high
specificity and efficiency. In an effort to mimic the structure and functionality of enzymes …

Supramolecular catalysis in metal–ligand cluster hosts

CJ Brown, FD Toste, RG Bergman… - Chemical …, 2015 - ACS Publications
Supramolecular chemistry aims to exploit the intermolecular interaction as an alternative
basis for control over chemical reactivity. Where synthetic chemists typically covalently …

Chiral metallosupramolecular architectures

LJ Chen, HB Yang, M Shionoya - Chemical Society Reviews, 2017 - pubs.rsc.org
Over the past few decades, supramolecular chirality in discrete metallosupramolecular
architectures has received considerable attention. In this review, a comprehensive summary …

Supramolecular coordination: self-assembly of finite two-and three-dimensional ensembles

R Chakrabarty, PS Mukherjee, PJ Stang - Chemical reviews, 2011 - ACS Publications
Fascination with supramolecular chemistry over the past few decades has led to the
synthesis of an ever-increasing number of elegant and intricate functional structures with …

Transition metal catalysis in living cells: progress, challenges, and novel supramolecular solutions

CC James, B de Bruin, JNH Reek - Angewandte Chemie, 2023 - Wiley Online Library
The importance of transition metal catalysis is exemplified by its wide range of applications,
for example in the synthesis of chemicals, natural products, and pharmaceuticals. However …

Catechol‐based biomimetic functional materials

J Sedó, J Saiz‐Poseu, F Busqué… - Advanced …, 2013 - Wiley Online Library
Catechols are found in nature taking part in a remarkably broad scope of biochemical
processes and functions. Though not exclusively, such versatility may be traced back to …

Noncovalent interactions in Ir-catalyzed C–H activation: L-shaped ligand for para-selective borylation of aromatic esters

ME Hoque, R Bisht, C Haldar… - Journal of the American …, 2017 - ACS Publications
An efficient strategy for the para-selective borylation of aromatic esters is described. For
achieving high para-selectivity, a new catalytic system has been developed modifying the …

Enzyme mimics based upon supramolecular coordination chemistry

MJ Wiester, PA Ulmann… - Angewandte Chemie …, 2011 - Wiley Online Library
Recent advances in supramolecular coordination chemistry have allowed chemists to
synthesize macromolecular complexes that exhibit various properties intrinsic to enzymes …