MOF-polymer hybrid materials: from simple composites to tailored architectures

M Kalaj, KC Bentz, S Ayala Jr, JM Palomba… - Chemical …, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are inherently crystalline, brittle porous solids.
Conversely, polymers are flexible, malleable, and processable solids that are used for a …

Possible chemical and physical scenarios towards biological homochirality

Q Sallembien, L Bouteiller, J Crassous… - Chemical Society …, 2022 - pubs.rsc.org
The single chirality of biological molecules in terrestrial biology raises more questions than
certitudes about its origin. The emergence of biological homochirality (BH) and its …

Seeing the light: advancing materials chemistry through photopolymerization

N Corrigan, J Yeow, P Judzewitsch… - Angewandte Chemie …, 2019 - Wiley Online Library
The application of photochemistry to polymer and material science has led to the
development of complex yet efficient systems for polymerization, polymer post …

From precision polymers to complex materials and systems

JF Lutz, JM Lehn, EW Meijer… - Nature Reviews Materials, 2016 - nature.com
Complex chemical systems, such as living biological matter, are highly organized structures
based on discrete molecules in constant dynamic interactions. These natural materials can …

Efficient separation of enantiomers using stereoregular chiral polymers

J Shen, Y Okamoto - Chemical reviews, 2016 - ACS Publications
Biosystems, including ourselves, are very sensitive to the chirality of compounds; for
instance, monosodium L-glutamate is tasty, while its D-isomer is tasteless, and in many …

Atom transfer radical polymerization (ATRP): current status and future perspectives

K Matyjaszewski - Macromolecules, 2012 - ACS Publications
Current status and future perspectives in atom transfer radical polymerization (ATRP) are
presented. Special emphasis is placed on mechanistic understanding of ATRP, recent …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Polymerization of polar monomers mediated by main-group Lewis acid–base pairs

M Hong, J Chen, EYX Chen - Chemical reviews, 2018 - ACS Publications
The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …

New avenues for ligand-mediated processes–expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands

DLJ Broere, R Plessius, JI van der Vlugt - Chemical Society Reviews, 2015 - pubs.rsc.org
Redox-active ligands have evolved from being considered spectroscopic curiosities–
creating ambiguity about formal oxidation states in metal complexes–to versatile and useful …

Covalent organic frameworks: chemical approaches to designer structures and built‐in functions

X Chen, K Geng, R Liu, KT Tan, Y Gong… - Angewandte Chemie …, 2020 - Wiley Online Library
A new approach has been developed to design organic polymers using topology diagrams.
This strategy enables covalent integration of organic units into ordered topologies and …