Water: A tale of two liquids

P Gallo, K Amann-Winkel, CA Angell… - Chemical …, 2016 - ACS Publications
Water is the most abundant liquid on earth and also the substance with the largest number
of anomalies in its properties. It is a prerequisite for life and as such a most important subject …

Advances in computational studies of the liquid–liquid transition in water and water-like models

JC Palmer, PH Poole, F Sciortino… - Chemical …, 2018 - ACS Publications
There has been uninterrupted interest in supercooled water ever since the pioneering
experiments of Speedy and Angell revealed sharp increases in this substance's response …

Experimental observation of the liquid-liquid transition in bulk supercooled water under pressure

KH Kim, K Amann-Winkel, N Giovambattista, A Späh… - Science, 2020 - science.org
We prepared bulk samples of supercooled liquid water under pressure by isochoric heating
of high-density amorphous ice to temperatures of 205±10 kelvin, using an infrared …

Realistic phase diagram of water from “first principles” data-driven quantum simulations

SL Bore, F Paesani - Nature communications, 2023 - nature.com
Since the experimental characterization of the low-pressure region of water's phase diagram
in the early 1900s, scientists have been on a quest to understand the thermodynamic …

Second critical point in two realistic models of water

PG Debenedetti, F Sciortino, GH Zerze - Science, 2020 - science.org
The hypothesis that water has a second critical point at deeply supercooled conditions was
formulated to provide a thermodynamically consistent interpretation of numerous …

Signatures of a liquid–liquid transition in an ab initio deep neural network model for water

TE Gartner III, L Zhang, PM Piaggi… - Proceedings of the …, 2020 - National Acad Sciences
The possible existence of a metastable liquid–liquid transition (LLT) and a corresponding
liquid–liquid critical point (LLCP) in supercooled liquid water remains a topic of much …

Maxima in the thermodynamic response and correlation functions of deeply supercooled water

KH Kim, A Späh, H Pathak, F Perakis, D Mariedahl… - Science, 2017 - science.org
Femtosecond x-ray laser pulses were used to probe micrometer-sized water droplets that
were cooled down to 227 kelvin in vacuum. Isothermal compressibility and correlation length …

[HTML][HTML] Liquid–liquid transition and polyamorphism

H Tanaka - The Journal of Chemical Physics, 2020 - pubs.aip.org
Two or more liquid states may exist even for single-component substances, which is known
as liquid polymorphism, and the transition between them is called liquid–liquid transition …

Metastable liquid–liquid transition in a molecular model of water

JC Palmer, F Martelli, Y Liu, R Car… - Nature, 2014 - nature.com
Liquid water's isothermal compressibility and isobaric heat capacity, and the magnitude of its
thermal expansion coefficient, increase sharply on cooling below the equilibrium freezing …

Ultrafast X-ray probing of water structure below the homogeneous ice nucleation temperature

JA Sellberg, C Huang, TA McQueen, ND Loh… - Nature, 2014 - nature.com
Water has a number of anomalous physical properties, and some of these become
drastically enhanced on supercooling below the freezing point. Particular interest has …