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Metal–organic framework magnets
Metal–organic frameworks represent the ultimate chemical platform on which to develop a
new generation of designer magnets. In contrast to the inorganic solids that have dominated …
new generation of designer magnets. In contrast to the inorganic solids that have dominated …
Designing disorder into crystalline materials
Crystals are a state of matter characterized by periodic order. Yet, crystalline materials can
harbour disorder in many guises, such as non-repeating variations in composition, atom …
harbour disorder in many guises, such as non-repeating variations in composition, atom …
Dy (OH) 3: a paramagnetic magnetocaloric material for hydrogen liquefaction
The magnetic properties of a series of Ln (OH) 3 (where Ln= Gd–Er) coordination polymer
materials have been examined to evaluate their potential as magnetocaloric materials. Dy …
materials have been examined to evaluate their potential as magnetocaloric materials. Dy …
Microscopic mechanism for intrinsic nonlinear anomalous Hall conductivity in noncollinear antiferromagnetic metals
We theoretically investigate an intrinsic nonlinear anomalous Hall effect (INAHE) in space-
time (PT) symmetric antiferromagnetic metals. The INAHE is characterized by an asymmetric …
time (PT) symmetric antiferromagnetic metals. The INAHE is characterized by an asymmetric …
Hierarchical Assembly of Coordination Macromolecules with Atypical Geometries: Gd44Co28 Crown and Gd95Co60 Cage
MH Du, DH Wang, LW Wu, LP Jiang… - Angewandte Chemie …, 2022 - Wiley Online Library
The discovered giant clusters are always highly symmetric owing to the spontaneous
assembly of one or two basic units. Herein we report the Gd44Co28 crown and Gd95Co60 …
assembly of one or two basic units. Herein we report the Gd44Co28 crown and Gd95Co60 …
Development of magnetocaloric coordination polymers for low temperature cooling
Caloric materials have attracted significant interest as replacements for conventional
refrigeration, which is becoming increasingly important in our daily lives, yet poses issues for …
refrigeration, which is becoming increasingly important in our daily lives, yet poses issues for …
NaGdS2: A Promising Sulfide for Cryogenic Magnetic Cooling
The development of effective and eco-friendly cooling technology demands an investigation
of new magnetocaloric materials. Compounds containing gadolinium are one of the best …
of new magnetocaloric materials. Compounds containing gadolinium are one of the best …
Pair distribution functions from neutron total scattering for the study of local structure in disordered materials
With the development of pulsed spallation sources of neutrons in recent years has come the
possibility to generate intense beams of higher energy than possible at reactor sources. This …
possibility to generate intense beams of higher energy than possible at reactor sources. This …
Magnetic properties and magnetocaloric effect of Ln= Dy, Tb carborane-based metal–organic frameworks
We present the synthesis and magneto-thermal properties of carborane-based lanthanide
metal–organic frameworks (MOFs) with the formula {[(Ln) 3 (mCB-L) 4 (NO3)(DMF) n]· Solv} …
metal–organic frameworks (MOFs) with the formula {[(Ln) 3 (mCB-L) 4 (NO3)(DMF) n]· Solv} …
Multifunctional self-refrigerated multivariate {GdLn}(Ln= Dy, Tb, Tb/Eu) metal–organic frameworks
Multivariate metal–organic frameworks (MOFs) containing multiple lanthanide ions present a
compelling avenue for develo** versatile materials with tailored properties. In this work …
compelling avenue for develo** versatile materials with tailored properties. In this work …