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Polyolefin thermoplastic elastomers from polymerization catalysis: Advantages, pitfalls and future challenges
Polyolefins have dominated materials technology over the last century and remain among
the most used materials, despite environmental problems have emerged and their public …
the most used materials, despite environmental problems have emerged and their public …
FI Catalysts for olefin polymerization A comprehensive treatment
H Makio, H Terao, A Iwashita, T Fujita - Chemical reviews, 2011 - ACS Publications
1.1. General Overview Polyolefinic materials, exemplified by polyethylenes (PEs),
polypropylenes (PPs), and ethylene/R-olefin amorphous copolymers, display many notable …
polypropylenes (PPs), and ethylene/R-olefin amorphous copolymers, display many notable …
Direct synthesis of thermoplastic polyolefin elastomers from nickel-catalyzed ethylene polymerization
As a promising alternative to thermoset elastomers, thermoplastic elastomers (TPEs) have
attracted much attention because of their unique properties, including processability …
attracted much attention because of their unique properties, including processability …
Synthesis of polyolefin elastomers from unsymmetrical α-diimine nickel catalyzed olefin polymerization
Due to a unique chain walking process, α-diimine nickel catalysts produce variously
branched polyolefins using only ethylene as the feedstock. Ligand structures and …
branched polyolefins using only ethylene as the feedstock. Ligand structures and …
Heterogeneous nickel catalysts for the synthesis of ethylene-based polyolefin elastomers
Z Bi, J Zhou, N Zhu, D Peng, C Chen - Macromolecules, 2024 - ACS Publications
Ethylene-based polyolefin elastomers (EPOEs) represent a novel class of polyolefin material
prepared using ethylene as the only feedstock and bear comparable mechanical and elastic …
prepared using ethylene as the only feedstock and bear comparable mechanical and elastic …
Chemically crosslinked crystalline thermoplastic polyolefin elastomer with good elasticity and improved thermo-mechanical properties
Y Zhao, Y Ma, Y **ong, T Qin, Y Zhu, H Deng, J Qin… - Polymer, 2022 - Elsevier
Due to mechanical α-relaxation process, olefin block copolymer (OBC) has a limited heat
resistance and thermo-mechanical property. In this work, peroxide-induced melt crosslinking …
resistance and thermo-mechanical property. In this work, peroxide-induced melt crosslinking …
Ni (II) α-diimine-catalyzed α-olefins polymerization: thermoplastic elastomers of block copolymers
The polymerization of ethylene with late transition metal complexes typically provides highly
branched amourphous poly (ethylene) s through a chain-walking mechanism, while the …
branched amourphous poly (ethylene) s through a chain-walking mechanism, while the …
One-step reactive processing of vitrimeric thermoplastic polyolefin elastomer with greatly improved thermo-mechanical property
Y Zhao, J Li, Y Ma, Y Wang, C Jiang, H Yan, R Hao… - Polymer, 2023 - Elsevier
Chemically crosslinking can enhance mechanical strength, dimensional stability and heat-
resistance of thermoplastic polyolefin elastomers. However, chemically crosslinked …
resistance of thermoplastic polyolefin elastomers. However, chemically crosslinked …
Difunctional olefin block copolymer/paraffin form-stable phase change materials with simultaneous shape memory property
Q Zhang, J Feng - Solar energy materials and solar cells, 2013 - Elsevier
In this work, a novel sort of form-stable phase change materials (FSPCMs) which possesses
simultaneously the shape memory function was designed and prepared. The FSPCMs …
simultaneously the shape memory function was designed and prepared. The FSPCMs …
Vitrimers of polyolefin elastomer with physically cross-linked network
Dynamics of exchange within vitrimer networks are influenced by mobility of the chemical
species involved in the exchange reaction, then it can be affected by the crystalline phase …
species involved in the exchange reaction, then it can be affected by the crystalline phase …