Atoms in molecules in real space: a fertile field for chemical bonding

ÁM Pendás, E Francisco, D Suárez… - Physical Chemistry …, 2023 - pubs.rsc.org
In this perspective, we review some recent advances in the concept of atoms-in-molecules
from a real space perspective. We first introduce the general formalism of atomic weight …

Carboxylic acid directed γ-lactonization of unactivated primary C–H bonds catalyzed by Mn complexes: application to stereoselective natural product diversification

A Call, M Cianfanelli, P Besalú-Sala… - Journal of the …, 2022 - ACS Publications
Reactions that enable selective functionalization of strong aliphatic C–H bonds open new
synthetic paths to rapidly increase molecular complexity and expand chemical space …

σ‐Noninnocence: Masked Phenyl‐Cation Transfer at Formal NiIV

JS Steen, G Knizia, JEMN Klein - … Chemie International Edition, 2019 - Wiley Online Library
Reductive elimination is an elementary organometallic reaction step involving a formal
oxidation state change of− 2 at a transition‐metal center. For a series of formal high‐valent …

The oxidation state in low-valent beryllium and magnesium compounds

M Gimferrer, S Danés, E Vos, CB Yildiz, I Corral… - Chemical …, 2022 - pubs.rsc.org
Low-valent group 2 (E= Be and Mg) stabilized compounds have been long synthetically
pursued. Here we discuss the electronic structure of a series of Lewis base-stabilized Be …

Oxidation States: Intrinsically Ambiguous?

IF Leach, JEMN Klein - ACS central science, 2024 - ACS Publications
The oxidation state (OS) formalism is a much-appreciated good in chemistry, receiving wide
application. However, like all formalisms, limitations are inescapable, some of which have …

High-performance electrochemical detection of glucose in human blood serum using a hierarchical NiO2 nanostructure supported on phosphorus doped graphene

S Tamilarasi, RS Kumar, KB Cho, CJ Kim… - Materials Today …, 2023 - Elsevier
This report describes the development of high-performing non-enzymatic glucose sensors
based on a combination of a phosphorous doped graphene (PG) layer and a composite …

Reply to the 'Comment on “The oxidation state in low-valent beryllium and magnesium compounds”'by S. Pan and G. Frenking, Chem. Sci., 2022, 13

M Gimferrer, S Danés, E Vos, CB Yildiz, I Corral… - Chemical …, 2023 - pubs.rsc.org
A recent article by Pan and Frenking challenges our assignment of the oxidation state of low
valent group 2 compounds. With this reply, we show that our assignment of Be (+ 2) and Mg …

Does serial femtosecond crystallography depict state-specific catalytic intermediates of the oxygen-evolving complex?

M Drosou, G Comas-Vilà, F Neese… - Journal of the …, 2023 - ACS Publications
Recent advances in serial femtosecond crystallography (SFX) of photosystem II (PSII),
enabled by X-ray free electron lasers (XFEL), provided the first geometric models of distinct …

Single-Atom AuI–N3 Site for Acetylene Hydrochlorination Reaction

Z Chen, Y Chen, S Chao, X Dong, W Chen, J Luo… - Acs …, 2020 - ACS Publications
The gold-catalyzed acetylene hydrochlorination reaction is an important process to produce
vinyl chloride monomer in the polyvinyl chloride industry. The traditional catalyst of carbon …

How Aromatic Are Molecular Nanorings? The Case of a Six‐Porphyrin Nanoring

I Casademont‐Reig, R Guerrero‐Avilés… - Angewandte …, 2021 - Wiley Online Library
Large conjugated rings with persistent currents are novel promising structures in molecular‐
scale electronics. A six‐porphyrin nanoring structure that allegedly sustained an aromatic …