Vanadium fluorophosphates: advanced cathode materials for next-generation secondary batteries

S Xu, Y Yang, F Tang, Y Yao, X Lv, L Liu, C Xu… - Materials …, 2023 - pubs.rsc.org
Next-generation secondary batteries including sodium-ion batteries (SIBs) and potassium-
ion batteries (PIBs) are considered the most promising candidates for application to large …

Trimming the Degrees of Freedom via a K+ Flux Rectifier for Safe and Long-Life Potassium-Ion Batteries

X Yi, AM Rao, J Zhou, B Lu - Nano-Micro Letters, 2023 - Springer
High degrees of freedom (DOF) for K+ movement in the electrolytes is desirable, because
the resulting high ionic conductivity helps improve potassium-ion batteries, yet requiring …

KTiOPO4-structured electrode materials for metal-ion batteries: A review

SS Fedotov, AS Samarin, EV Antipov - Journal of Power Sources, 2020 - Elsevier
The success story of the triphylite-type LiFePO 4 immediately boosted the development of
numerous classes of polyanion-based electrode materials for metal-ion batteries. A number …

A dilute fluorinated phosphate electrolyte enables 4.9 V‐class potassium ion full batteries

Y Gao, W Li, B Ou, S Zhang, H Wang… - Advanced Functional …, 2023 - Wiley Online Library
Potassium ion batteries using graphite anode and high‐voltage cathodes are considered to
be optimizing candidates for large‐scale energy storage. However, the lack of suitable …

Development of vanadium-based polyanion positive electrode active materials for high-voltage sodium-based batteries

SD Shraer, ND Luchinin, IA Trussov… - Nature …, 2022 - nature.com
Polyanion compounds offer a playground for designing prospective electrode active
materials for sodium-ion storage due to their structural diversity and chemical variety. Here …

Synthesis of KVPO4F/Carbon Porous Single Crystalline Nanoplates for High-Rate Potassium-Ion Batteries

J Liao, X Zhang, Q Zhang, Q Hu, Y Li, Y Du, J Xu… - Nano Letters, 2022 - ACS Publications
With high theoretical capacity and operating voltage, KVPO4F is a potential high energy
density cathode material for potassium-ion batteries. However, its performance is usually …

Regulating cathode surface hydroxyl chemistry enables superior potassium storage

Q Fu, C Peng, W Zhou, X Zhang… - Proceedings of the …, 2023 - National Acad Sciences
Potassium vanadium fluorophosphate (KVPO4F) is regarded as a promising cathode
candidate for potassium-ion batteries due to its high working voltage and satisfactory …

Carbene-catalyzed synthesis of a fluorophosphate cathode

Q Fu, W Zhou, P Gao, H Dong, S Chen… - Energy & …, 2024 - pubs.rsc.org
Fluorophosphate compounds are an important class of cathode materials; however, the one-
step synthesis of phase-pure fluorophosphate compounds in a well-controlled manner …

XPS analysis of K-based reference compounds to allow reliable studies of solid electrolyte interphase in K-ion batteries

L Caracciolo, L Madec, H Martinez - ACS Applied Energy …, 2021 - ACS Publications
As for Li-and Na-ion batteries, the electrolyte reactivity (ie, the salt and solvent
decomposition) also plays a crucial role in the electrochemical performance of K-ion …

Pomegranate‐Like KVPO4F@C Microspheres as High‐Volumetric‐Energy‐Density Cathode for Potassium‐Ion Batteries

C **e, X Liu, J Han, L Lv, X Zhou, C Han, Y You - Small, 2022 - Wiley Online Library
KVPO4F is one of the most competitive cathode candidates for potassium‐ion batteries
(KIBs) because of its high output voltage and energy density. Although the gravimetric …