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Optical phenomena in molecule-based magnetic materials
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …
deals with magnetic materials based on molecular species, ie, organic radicals and metal …
Metal–organic framework magnets
Metal–organic frameworks represent the ultimate chemical platform on which to develop a
new generation of designer magnets. In contrast to the inorganic solids that have dominated …
new generation of designer magnets. In contrast to the inorganic solids that have dominated …
Electronic conductivity, ferrimagnetic ordering, and reductive insertion mediated by organic mixed-valence in a ferric semiquinoid metal–organic framework
A three-dimensional network solid composed of FeIII centers and paramagnetic semiquinoid
linkers,(NBu4) 2FeIII2 (dhbq) 3 (dhbq2–/3–= 2, 5-dioxidobenzoquinone/1, 2-dioxido-4, 5 …
linkers,(NBu4) 2FeIII2 (dhbq) 3 (dhbq2–/3–= 2, 5-dioxidobenzoquinone/1, 2-dioxido-4, 5 …
2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry
We report the magnetism and conductivity for a redox pair of iron-quinoid metal–organic
frameworks (MOFs). The oxidized compound,(Me2NH2) 2 [Fe2L3]· 2H2O· 6DMF (LH2= 2, 5 …
frameworks (MOFs). The oxidized compound,(Me2NH2) 2 [Fe2L3]· 2H2O· 6DMF (LH2= 2, 5 …
Metal-organic frameworks in Russia: From the synthesis and structure to functional properties and materials
MA Agafonov, EV Alexandrov, NA Artyukhova… - Journal of Structural …, 2022 - Springer
Current research fields of metal-organic frameworks (MOFs), which are being developed in
the last 5-10 years by Russian scientific institutions and universities, are generalized. The …
the last 5-10 years by Russian scientific institutions and universities, are generalized. The …
A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from Tc = 26 to 80 K
IR Jeon, B Negru, RP Van Duyne… - Journal of the American …, 2015 - ACS Publications
The incorporation of tetraoxolene radical bridging ligands into a microporous magnetic solid
is demonstrated. Metalation of the redox-active bridging ligand 2, 5-dichloro-3, 6-dihydroxy …
is demonstrated. Metalation of the redox-active bridging ligand 2, 5-dichloro-3, 6-dihydroxy …
Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [Fe III (acac 2-trien)]+ …
The syntheses, structures and magnetic properties of the coordination compounds of
formula [FeIII (acac2-trien)][MnIICrIII (Cl2 An) 3]·(CH3CN) 2 (1),[FeIII (acac2-trien)][MnIICrIII …
formula [FeIII (acac2-trien)][MnIICrIII (Cl2 An) 3]·(CH3CN) 2 (1),[FeIII (acac2-trien)][MnIICrIII …
Control of electronic structure and conductivity in two-dimensional metal–semiquinoid frameworks of titanium, vanadium, and chromium
The isostructural, two-dimensional metal–organic frameworks (H2NMe2) 2M2 (Cl2dhbq) 3
(M= Ti, V; Cl2dhbq n–= deprotonated 2, 5-dichloro-3, 6-dihydroxybenzoquinone) and …
(M= Ti, V; Cl2dhbq n–= deprotonated 2, 5-dichloro-3, 6-dihydroxybenzoquinone) and …
Nanosheets of two-dimensional magnetic and conducting Fe (II)/Fe (III) mixed-valence metal–organic frameworks
We report the synthesis, magnetic properties, electrical conductivity, and delamination into
thin nanosheets of two anilato-based Fe (II)/Fe (III) mixed-valence two-dimensional metal …
thin nanosheets of two anilato-based Fe (II)/Fe (III) mixed-valence two-dimensional metal …
Mixed valency in a 3D semiconducting iron–fluoranilate coordination polymer
A pair of coordination polymers of composition (NBu4) 2 [M2 (fan) 3](fan= fluoranilate; M= Fe
and Zn) were synthesized and structurally characterized. In each case the compound …
and Zn) were synthesized and structurally characterized. In each case the compound …