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Halogen bonding and chalcogen bonding mediated sensing
Sigma–hole interactions, in particular halogen bonding (XB) and chalcogen bonding (ChB),
have become indispensable tools in supramolecular chemistry, with wide-ranging …
have become indispensable tools in supramolecular chemistry, with wide-ranging …
Fluorescent Flippers: Small‐Molecule Probes to Image Membrane Tension in Living Systems
Flipper probes have been introduced as small molecule fluorophores to image physical
forces, that is, membrane tension in living systems. Their emergence over one decade is …
forces, that is, membrane tension in living systems. Their emergence over one decade is …
Selective potassium chloride recognition, sensing, extraction, and transport using a chalcogen-bonding heteroditopic receptor
Chalcogen bonding (ChB) is rapidly rising to prominence in supramolecular chemistry as a
powerful sigma (σ)-hole-based noncovalent interaction, especially for applications in the …
powerful sigma (σ)-hole-based noncovalent interaction, especially for applications in the …
Redox-switchable chalcogen bonding for anion recognition and sensing
Inspired by the success of its related sigma-hole congener halogen bonding (XB),
chalcogen bonding (ChB) is emerging as a powerful noncovalent interaction with a plethora …
chalcogen bonding (ChB) is emerging as a powerful noncovalent interaction with a plethora …
Multistate redox-switchable ion transport using chalcogen-bonding anionophores
Synthetic supramolecular transmembrane anionophores have emerged as promising
anticancer chemotherapeutics. However, key to their targeted application is achieving …
anticancer chemotherapeutics. However, key to their targeted application is achieving …
Supramolecular chemistry in lipid bilayer membranes
Lipid bilayer membranes form compartments requisite for life. Interfacing supramolecular
systems, including receptors, catalysts, signal transducers and ion transporters, enables the …
systems, including receptors, catalysts, signal transducers and ion transporters, enables the …
Modulating chalcogen bonding and halogen bonding sigma‐hole donor atom potency and selectivity for halide anion recognition
A series of acyclic anion receptors containing chalcogen bond (ChB) and halogen bond
(XB) donors integrated into a neutral 3, 5‐bis‐triazole pyridine scaffold are described, in …
(XB) donors integrated into a neutral 3, 5‐bis‐triazole pyridine scaffold are described, in …
Tunable Pnictogen Bonding at the Service of Hydroxide Transport across Phospholipid Bilayers
Our growing interest in the design of pnictogen-based strategies for anion transport has
prompted an investigation into the properties of three simple triarylcatecholatostiboranes (1 …
prompted an investigation into the properties of three simple triarylcatecholatostiboranes (1 …
Anion transporters based on halogen, chalcogen, and pnictogen bonds: towards biological applications
Motivated by their potential biological applications, anion receptors are increasingly
explored as transmembrane transporters for anions. The vast majority of the reported anion …
explored as transmembrane transporters for anions. The vast majority of the reported anion …
Anti‐Hofmeister Anion Selectivity via a Mechanical Bond Effect in Neutral Halogen‐Bonding [2] Rotaxanes
Exceptionally strong halogen bonding (XB) donor‐chloride interactions are exploited for the
chloride anion template synthesis of neutral XB [2] rotaxane host systems which contain …
chloride anion template synthesis of neutral XB [2] rotaxane host systems which contain …