Selectivity of C–H activation and competition between C–H and C–F bond activation at fluorocarbons

O Eisenstein, J Milani, RN Perutz - Chemical Reviews, 2017 - ACS Publications
Partially fluorinated alkanes, arenes, and alkenes can be transformed by a variety of
transition metal and lanthanide systems. Although the C–H bond is weaker than the C–F …

Overcoming spectral overlap via inductively coupled plasma-tandem mass spectrometry (ICP-MS/MS). A tutorial review

E Bolea-Fernandez, L Balcaen, M Resano… - Journal of Analytical …, 2017 - pubs.rsc.org
This work reviews the operating principles of ICP-tandem mass spectrometry (ICP-MS/MS)
and the key applications reported on since the introduction of the technique in 2012. The …

Potential of methyl fluoride as a universal reaction gas to overcome spectral interference in the determination of ultratrace concentrations of metals in biofluids using …

E Bolea-Fernandez, L Balcaen, M Resano… - Analytical …, 2014 - ACS Publications
Methyl fluoride (a mixture of 10% CH3F and 90% of He) was evaluated as a reaction gas in
inductively coupled plasma-tandem mass spectrometry (ICPMS/MS) in the context of the …

Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2013

FT Edelmann - Coordination Chemistry Reviews, 2015 - Elsevier
This review summarizes the progress in organo-f-element chemistry during the year 2013.
The year 2013 witnessed a significant increase of contributions in the fields of …

Experiment and Theory Clarify: Sc+ Receives One Oxygen Atom from SO2 to Form ScO+, which Proves to be a Catalyst for the Hidden Oxygen‐Exchange with SO2

JM Mercero, E Rezabal, JM Ugalde… - …, 2022 - Wiley Online Library
Using Fourier‐transform ion cyclotron resonance mass spectrometry, it was experimentally
determined that Sc+ in the highly diluted gas phase reacts with SO2 to form ScO+ and SO …

Halogen-abstraction reactions from chloromethane and bromomethane molecules by alkaline-earth monocations

P Redondo, A Largo, VM Rayón… - Physical Chemistry …, 2014 - pubs.rsc.org
The reactions, in the gas phase, between alkali-earth monocations (Mg+, Ca+, Sr+, Ba+)
and CH3X (X= Cl, Br) have been theoretically studied. The stationary points on the potential …

Kinetics Studies of the Reactions of Main Fourth-Period Monocations (Ga+, Ge+, As+, and Se+) with Methyl Fluoride

C Barrientos, VM Rayón, A Largo… - The Journal of …, 2013 - ACS Publications
Thermodynamics and kinetics theoretical studies on the gas-phase reactions of
fluoromethane with main fourth-period monocations (Ga+, Ge+, As+, and Se+) have been …

Formation of gas-phase metal fluorides in reactions of fluorinated fullerenes at activated metal surfaces

AV Streletskiy, ID Kellner, LC Nye, T Drewello… - Journal of Fluorine …, 2017 - Elsevier
A comparative investigation into the chemical reactions of a series of fluorinated fullerenes
(C 60 F 18, C 60 F 36 and C 60 F 48) with a variety of activated metal surfaces is reported …

Modelización computacional de la reactividad química: reacción de Ge++ CH3X (Cl, Br)

J Abellán Burgos - 2016 - uvadoc.uva.es
Se ha llevado a cabo un estudio computacional para las reacciones del catión germanio
con clorometano y bromometano. El estudio se ha realizado dentro del contexto de la teoría …

Activación de enlaces carbono-halógeno por cationes metálicos: estudio de la reacción (Zn+)+(CH3Cl)

A Ruiz Echávarri - 2015 - uvadoc.uva.es
Se ha llevado a cabo un estudio teórico-computacional sobre la reacción Zn++ CH3Cl. El
estudio se ha realizado dentro del contexto de la teoría del funcional de la densidad (DFT) …