NMR spectroscopy in glass science: a review of the elements

R Youngman - Materials, 2018 - mdpi.com
The study of inorganic glass structure is critically important for basic glass science and
especially the commercial development of glasses for a variety of technological uses. One of …

NMR studies of oxide-based glasses

M Edén - Annual Reports Section" C"(Physical Chemistry), 2012 - pubs.rsc.org
Solid-state nuclear magnetic resonance (NMR) spectroscopy offers an array of options for
exploring structural order of amorphous materials both over short (≲ 0.3 nm) and medium (≲ …

Acid-based geopolymers: Understanding of the structural evolutions during consolidation and after thermal treatments

V Mathivet, J Jouin, A Gharzouni, I Sobrados… - Journal of Non …, 2019 - Elsevier
Materials such as ceramic matrix composites are developed for mechanical applications at
high temperature, but their cost remains a limitation. Consequently, the use of acid-based …

A review on immobilization of phosphate containing high level nuclear wastes within glass matrix–Present status and future challenges

P Sengupta - Journal of Hazardous Materials, 2012 - Elsevier
Immobilization of phosphate containing high level nuclear wastes within commonly used
silicate glasses is difficult due to restricted solubility of P2O5 within such melts and its …

Update on 27Al NMR studies of aluminosilicate glasses

M Eden - Annual reports on NMR spectroscopy, 2020 - Elsevier
Aluminosilicate glasses and melts are of great geological and technological importance.
Significant efforts have been spent for enhancing the insight into their structures. Here magic …

[HTML][HTML] Probing oxide-based glass structures by solid-state NMR: Opportunities and limitations

M Edén - Journal of Magnetic Resonance Open, 2023 - Elsevier
This Primer critically reviews the possibilities and limitations of probing the short-range
structure of an oxide-based glass by routine magic-angle spinning (MAS) or triple-quantum …

Structural features and rare earth ion clustering behavior in lanthanum phosphate and aluminophosphate glasses from molecular dynamics simulations

MI Tuheen, J Du - Journal of Non-Crystalline Solids, 2022 - Elsevier
This paper reports detailed short and medium range structural features of lanthanum oxide
containing alkaline phosphate and aluminophosphate glasses revealed from molecular …

The D-HMQC MAS-NMR technique: An efficient tool for the editing of through-space correlation spectra between quadrupolar and spin-1/2 (31P, 29Si, 1H, 13C) nuclei

G Tricot, J Trebosc, F Pourpoint, R Gauvin… - Annual Reports on NMR …, 2014 - Elsevier
The D-HMQC (dipolar heteronuclear multiple-quantum coherence) technique is a recently
developed NMR pulse sequence particularly suitable for the investigation of spatial …

Relation between working properties and structural properties from 27Al, 29Si and 31P NMR and XRD of acid-based geopolymers from 25 to 1000° C

H Celerier, J Jouin, A Gharzouni, V Mathivet… - Materials Chemistry and …, 2019 - Elsevier
Acid-based geopolymers exhibit interesting properties, such as higher temperature
resistance (up to 1450° C) and better mechanical properties, as compared to alkali-based …

Fire resistance of phosphoric acid activated metakaolin geopolymer

Q Yang, C Davy, J Sarazin, S Bourbigot… - … and Building Materials, 2024 - Elsevier
Fire resistance is a key advantage of geopolymer (GP) materials. While most research
focuses on alkali-activated GPs, this study examines the fire resistance of phosphoric acid …