Hydrogenation of carboxylic acids, esters, and related compounds over heterogeneous catalysts: a step toward sustainable and carbon-neutral processes

R Qu, K Junge, M Beller - Chemical Reviews, 2023 - ACS Publications
The catalytic hydrogenation of esters and carboxylic acids represents a fundamental and
important class of organic transformations, which is widely applied in energy, environmental …

Recent advances in the routes and catalysts for ethanol synthesis from syngas

G Liu, G Yang, X Peng, J Wu, N Tsubaki - Chemical Society Reviews, 2022 - pubs.rsc.org
Ethanol, as one of the important bulk chemicals, is widely used in modern society. It can be
produced by fermentation of sugar, petroleum refining, or conversion of syngas (CO/H2) …

Copper phyllosilicate nanotube catalysts for the chemosynthesis of cyclohexane via hydrodeoxygenation of phenol

H Wang, W Zhao, MU Rehman, W Liu, Y Xu… - ACS …, 2022 - ACS Publications
In the utilization of renewable resources derived from biomass, hydrodeoxygenation (HDO)
is one of the most critical steps in the bio-oil upgrading process. Herein, a series of copper …

Steric-confinement Rh2/MoS2 dual-atom catalyst directionally modulating adsorption configuration of ester group to boost ethanol synthesis

Y Zhao, Q Gu, X Sun, D Wang, X Gong, B Yang, J Xu… - Chem, 2024 - cell.com
Develo** a new tactic for directionally regulating a specific functional group of feedstock
molecules at the molecular level is highly desired to synthesize high-value products but …

Perspectives on the active sites and catalyst design for the hydrogenation of dimethyl oxalate

RP Ye, L Lin, LC Wang, D Ding, Z Zhou, P Pan… - ACS …, 2020 - ACS Publications
What should people do with the huge amount of CO2 captured? CO2 to CO is a promising
way for using carbon resources because CO is one component of syngas for the production …

Interface tuning of Cu+/Cu0 by zirconia for dimethyl oxalate hydrogenation to ethylene glycol over Cu/SiO2 catalyst

Y Zhao, H Zhang, Y Xu, S Wang, Y Xu, S Wang… - Journal of Energy …, 2020 - Elsevier
Abstract An efficient ZrO 2–doped Cu/SiO 2 catalyst was fabricated through hydrolysis
precipitation method (HP) and used to produce ethylene glycol (EG) through dimethyl …

Understanding the synergistic catalysis in hydrogenation of carbonyl groups on Cu-based catalysts

QN Wang, R Duan, Z Feng, Y Zhang, P Luan… - ACS …, 2024 - ACS Publications
Understanding the synergy of Cu0 and Cu+ in hydrogenation reactions is indispensable for
reasonably modulating the product distributions and improving the catalyst design. Herein …

Elevating dimethyl oxalate hydrogenation activity over core–shell Cu/SiO2@ CeO2 catalysts

Z Ma, Y Li, Z Li, Z Liu, X Wang, Y Tan, X Chen… - Chemical Engineering …, 2024 - Elsevier
Increasing dimethyl oxalate (DMO) hydrogenation activity remains a challenge. A Cu
catalyst was designed by creating Cu nanoparticles (NPs) over SiO 2 layer formed on the …

Boosting hydrogenation properties of supported Cu-based catalysts by replacing Cu0 active sites

B Kang, Z Chen, J Yang, M Lv, H He, G Chen… - Applied Catalysis B …, 2025 - Elsevier
Abstract Balancing the Cu+/Cu 0 ratio is a common strategy to improve catalytic activity of
Cu-based catalysts but is still constrained by low atomic utilization and the inherent nature of …

Construction of Cu-Ce composite oxides by simultaneous ammonia evaporation method to enhance catalytic performance of Ce-Cu/SiO2 catalysts for dimethyl …

CC Chen, L Lin, RP Ye, L Huang, LB Zhu, YY Huang… - Fuel, 2021 - Elsevier
The complicated ammonia evaporation method (AEM) involves many steps, such as mixing,
evaporating ammonia, drying, and calcining procedures, etc. Thus it is necessary to know in …