The hydroformylation of olefins is one of the most important homogeneously catalyzed
processes in industry to produce bulk chemicals. Despite the high catalytic activities and …

This review deals with heterogeneous hydroformylation catalysts, specifically metal
complexes fixed in an organic polymer structure. It describes the main catalyst synthesis …

A heterogeneous ruthenium catalyst consisting of isolated single atoms and disordered
clusters stabilized in a N-doped carbon matrix has been synthesized with very good activity …

The reaction mechanisms of heterogeneous hydroformylation of ethylene and propylene
were compared at 413–453 K using RhCo3/MCM-41 as catalysts. The reaction rates of …

The design and construction of Rh-based heterogeneous catalysts with excellent catalytic
activity and high atom utilization for hydroformylation of olefins is extremely important but still …

Vinyl functionalized Xantphos ligand (denoted as 4v-Xantphos) was newly synthesized and
successfully doped into the PPh 3 based porous organic polymers (POPs) through the …

Single-atom Rh catalysts have been reported to exhibit high activity in olefin
hydroformylation, yet with limited regioselectivity. We develop a Xantphos ligand …

Catalysts for hydroformylation of ethene were prepared by grafting Rh into nests of≡ SiOZn–
OH or≡ SiOCo–OH species prepared in dealuminated BEA zeolite. X-ray absorption …

Olefin hydroformylation is a widely used process, both on large scales and in fine chemistry,
with catalyst reuse still being one of the main objectives. In recent years, developments in …

A method for the synthesis of highly crystalline Rh2P nanoparticles on SiO2 support
materials and their use as truly heterogeneous single-site catalysts for the hydroformylation …