Recent advances in the chemistry of the phosphaethynolate and arsaethynolate anions

S Basappa, R Bhawar, DH Nagaraju, SK Bose - Dalton Transactions, 2022‏ - pubs.rsc.org
Over the past decade, the reactivity of 2-phosphaethynolate (OCP−), a heavier analogue of
the cyanate anion, has been the subject of momentous interest in the field of modern …

Understanding the Mechanism of Diels–Alder Reactions with Anionic Dienophiles: A Systematic Comparison of [ECX] (E = P, As; X = O, S, Se) Anions

Á Horváth, Z Benkő - Inorganic Chemistry, 2022‏ - ACS Publications
While Diels–Alder (DA) reactions involving neutral or cationic dienophiles are well-known,
the characteristics of the analogous reactions with anionic dienophiles are practically …

Bis‐Phosphaketenes LM(PCO)2 (M=Ga, In): A New Class of Reactive Group 13 Metal‐Phosphorus Compounds

MK Sharma, P Dhawan, C Helling… - … A European Journal, 2022‏ - Wiley Online Library
Phosphaketenes are versatile reagents in organophosphorus chemistry. We herein report
on the synthesis of novel bis‐phosphaketenes, LM (PCO) 2 (M= Ga 2 a, In 2 b; L= HC [C …

N‐Heterocyclic Carbene‐Assisted Reversible Migratory Coupling of Aminoborane at Magnesium

AD Obi, NC Frey, DA Dickie, CE Webster… - Angewandte …, 2022‏ - Wiley Online Library
A combined synthetic and theoretical investigation of N‐heterocyclic carbene (NHC) adducts
of magnesium amidoboranes is presented, which involves a rare example of reversible …

Deciphering the Differences in Ambident Reactivity between the Cyanate, Thiocyanate Ions, and their P‐and As‐Containing Analogues

Á Horváth, BD Lőrincz, Z Benkő - Chemistry–A European …, 2023‏ - Wiley Online Library
Although the cyanate and thiocyanate anions belong to the most known textbook examples
of ambident nucleophiles, the electronic factors that determine their markedly differing …

Synthesis and structures of molecular beryllium Grignard analogues featuring terminal and bridging pseudohalides

C Czernetzki, M Arrowsmith, M Jürgensen… - Dalton …, 2024‏ - pubs.rsc.org
The carbene-stabilised beryllium Grignards [(CAAC) BeBrR](R= CAACH 1a, Dur 1b;
CAAC/H= 1-(2, 6-diisopropylphenyl)-2, 2, 4, 4-tetramethylpyrrolidin-2-yl/idene; Dur= 2, 3, 5 …

Carbene–calcium silylamides and amidoboranes

AD Obi, LA Freeman, SJ Coates, AJH Alexis… - …, 2022‏ - ACS Publications
The stereoelectronic effects of N-heterocyclic carbene (NHC) and cyclic (alkyl)(amino)
carbene (CAAC) coordination to calcium silylamides and amidoboranes have been …

The Systematic Design of Nickel Complexes Toward Energy-Relevant Bond Activations

JR Prat - 2022‏ - search.proquest.com
The production of catalysts capable of the efficient and selective reactivity of CO 2, H 2, and
CO toward useful products is required to lower global energy costs and allow for a …

[معلومات الإصدار][C] Organometallic Complexes of the Alkaline Earth Metals

S Nembenna, N Sarkar, RK Sahoo, S Mukhopadhyay - 2022‏ - Elsevier