Metal oxide clusters, especially transition-metal polyoxometalates, have been studied for
decades because they provide a rare opportunity to study nanoscale materials with well …

Uranium complexes can be stabilized in a wide range of oxidation states, ranging from UII to
UVI and a very recent example of a UI complex. This review provides a comprehensive …

The uranyl ion,[UVIO2] 2+, possesses rigorously trans, strongly covalent, and chemically
robust U-oxo groups. However, through the use of anaerobic reaction techniques, both one …

The chemistry of the early to middle actinide elements (Th− Cm) is of critical importance to
the nuclear energy industry. A need for knowledge of the chemical behavior and speciation …

Most homogeneous catalysis relies on the design of metal complexes to trap and convert
substrates or small molecules to value‐added products. Organometallic lanthanide …

Since uranium has several common paramagnetic oxidation states, ie, 5f 1 U5+, 5f 2 U4+,
and 5f 3 U3+, one of the analytical methods commonly used for characterizing uranium …

Out of the 14 lanthanide (Ln) ions, molecular complexes of Ln (IV) were known only for
cerium and more recently terbium. Here we demonstrate that the+ IV oxidation state is also …

This chapter reviews the reaction chemistry of uranium complexes with small molecules of
industrial and biological importance. Specifically, carbon monoxide (CO), nitrogen monoxide …

Lead has been used as a heavy atom derivative to solve the phase problem in the crystal
structures of a variety of protein including the calcium proteins calmodulin and …

Discrete molecular compounds that exhibit both magnetization hysteresis and slow
magnetic relaxation below a characteristic 'blocking'temperature are known as single …