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Understanding MOF flexibility: an analysis focused on pillared layer MOFs as a model system
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …
their ability to open and close their pores in an adaptive manner induced by chemical and …
1H-Detected Biomolecular NMR under Fast Magic-Angle Spinning
T Le Marchand, T Schubeis, M Bonaccorsi… - Chemical …, 2022 - ACS Publications
Since the first pioneering studies on small deuterated peptides dating more than 20 years
ago, 1H detection has evolved into the most efficient approach for investigation of …
ago, 1H detection has evolved into the most efficient approach for investigation of …
Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries
Ni-rich layered cathode materials are among the most promising candidates for high-energy-
density Li-ion batteries, yet their degradation mechanisms are still poorly understood. We …
density Li-ion batteries, yet their degradation mechanisms are still poorly understood. We …
Graphite anodes for Li-ion batteries: an electron paramagnetic resonance investigation
Graphite is the most commercially successful anode material for lithium (Li)-ion batteries: its
low cost, low toxicity, and high abundance make it ideally suited for use in batteries for …
low cost, low toxicity, and high abundance make it ideally suited for use in batteries for …
NMR spectroscopy probes microstructure, dynamics and do** of metal halide perovskites
Solid-state magic-angle spinning NMR spectroscopy is a powerful technique to probe
atomic-level microstructure and structural dynamics in metal halide perovskites. It can be …
atomic-level microstructure and structural dynamics in metal halide perovskites. It can be …
Solid-state NMR spectroscopy
Solid-state nuclear magnetic resonance (NMR) spectroscopy is an atomic-level method to
determine the chemical structure, 3D structure and dynamics of solids and semi-solids. This …
determine the chemical structure, 3D structure and dynamics of solids and semi-solids. This …
Relativistic heavy-neighbor-atom effects on NMR shifts: Concepts and trends across the periodic table
Chemical shifts present crucial information about an NMR spectrum. They show the
influence of the chemical environment on the nuclei being probed. Relativistic effects …
influence of the chemical environment on the nuclei being probed. Relativistic effects …
Paramagnetic chemical probes for studying biological macromolecules
Paramagnetic chemical probes have been used in electron paramagnetic resonance (EPR)
and nuclear magnetic resonance (NMR) spectroscopy for more than four decades. Recent …
and nuclear magnetic resonance (NMR) spectroscopy for more than four decades. Recent …
Electrochemical ion insertion from the atomic to the device scale
Electrochemical ion insertion involves coupled ion–electron transfer reactions, transport of
guest species and redox of the host. The hosts are typically anisotropic solids with 2D …
guest species and redox of the host. The hosts are typically anisotropic solids with 2D …
Melting of hybrid organic–inorganic perovskites
Several organic–inorganic hybrid materials from the metal–organic framework (MOF) family
have been shown to form stable liquids at high temperatures. Quenching then results in the …
have been shown to form stable liquids at high temperatures. Quenching then results in the …