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A continuing legend: the Brookhart-type α-diimine nickel and palladium catalysts
F Wang, C Chen - Polymer Chemistry, 2019 - pubs.rsc.org
The Brookhart-type α-diimine nickel and palladium catalysts are one of the most examined
systems in the field of olefin polymerization. Even after more than twenty years of extensive …
systems in the field of olefin polymerization. Even after more than twenty years of extensive …
Spatiotemporal control for integrated catalysis
Integrated catalysis is an emerging methodology that can streamline the multi-step synthesis
of complicated products in a single reaction vessel, achieving a high degree of control and …
of complicated products in a single reaction vessel, achieving a high degree of control and …
Photoresponsive palladium and nickel catalysts for ethylene polymerization and copolymerization
D Peng, C Chen - Angewandte Chemie, 2021 - Wiley Online Library
In this contribution, we install an azobenzene functionality in olefin polymerization catalysts
and use light to modulate their properties via photoinduced trans–cis isomerization of the …
and use light to modulate their properties via photoinduced trans–cis isomerization of the …
Redox-controlled polymerization and copolymerization
C Chen - ACS Catalysis, 2018 - ACS Publications
Redox control is an attractive strategy for modulating polymerization processes as well as
the compositions, microstructures, and properties of polymer products. This perspective …
the compositions, microstructures, and properties of polymer products. This perspective …
Advances in polymerizations modulated by external stimuli
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …
within biological systems to obtain well-defined polymeric materials with unique structures …
Influence of Polyethylene Glycol Unit on Palladium‐and Nickel‐Catalyzed Ethylene Polymerization and Copolymerization
The transition‐metal‐catalyzed copolymerization of olefins with polar functionalized co‐
monomers represents a major challenge in the field of olefin polymerization. It is extremely …
monomers represents a major challenge in the field of olefin polymerization. It is extremely …
Tailoring metal complexes with N-heterocyclic carbene ligands using Electron-Withdrawing Groups: Impact on catalytic activity and property development
In the field of catalytic chemistry, metal complexes containing N-heterocyclic carbenes
(NHCs) have gained significant attention due to their versatile nature and wide range of …
(NHCs) have gained significant attention due to their versatile nature and wide range of …
Accessing multiple catalytically active states in redox-controlled olefin polymerization
M Zhao, C Chen - ACS Catalysis, 2017 - ACS Publications
The majority of work in the field of olefin polymerization catalysis has been focused on
ligand modifications. In this work, we describe an alternative strategy for the modulation of …
ligand modifications. In this work, we describe an alternative strategy for the modulation of …
Air-stable single-component Pd-catalysts for vinyl-addition polymerization of functionalized norbornenes
EV Bermesheva, EI Medentseva, AP Khrychikova… - ACS …, 2022 - ACS Publications
Well-defined single-component and tolerant Ru-, Mo-, and W-catalysts have been earlier
developed for ring-opening metathesis polymerization of norbornene and its derivatives …
developed for ring-opening metathesis polymerization of norbornene and its derivatives …
Recent developments in redox-active olefin polymerization catalysts
JM Kaiser, BK Long - Coordination Chemistry Reviews, 2018 - Elsevier
Olefin polymerization catalysis is an ever-growing and ever-evolving field that is of strategic
importance as scientists continually search for new methods to produce advanced polymeric …
importance as scientists continually search for new methods to produce advanced polymeric …