C− C bond formation is a fundamental transformation in organic synthesis. The development
of new synthetic methodology could be considered as a way of pursuing a novel method for …

The use of coordinating moieties as directing groups for the functionalization of aromatic C
H bonds has become an established tool to enhance reactivity and induce regioselectivity …

This communication describes the development of a room-temperature ligand-directed C–H
arylation reaction using aryldiazonium salts. This was achieved by the successful merger of …

The biheteroaryl structural motif is prevalent in polymers, advanced materials, liquid crystals,
ligands, molecules of medicinal interest, and natural products. Many types of synthetic …

We report the first example of ipso-borylation for the modular 1, 2-bisfunctionalization of aryl
iodides via C–H functionalization. The carbon–boron bond is used as a lynchpin to access …

The Rh (III)-catalyzed C–H functionalizations of benzamide derivatives with olefin were
studied by DFT calculations to elucidate the divergent pathways controlled by the N-OR …

The mechanism of the Ni-dcype-catalyzed C–H/C–O coupling of benzoxazole and
naphthalen-2-yl pivalate was studied. Special attention was devoted to the base effect in the …

Abstract Der Einsatz von koordinierenden Gruppen als dirigierende Gruppen ist eine
zuverlässige Methode zur Kontrolle von Reaktivität und Selektivität bei der Aktivierung von …

Pd-catalyzed meta-C–H chlorination of anilines and phenols is developed using norbornene
as the mediator. Heterocycles, including indole, thiophene, and indazole, are tolerated. The …

A system consisting of catalytic amounts of [(p‐cym) RuCl2] 2/PEt3⋅ HBF4, K2CO3 as the
base, and NMP as the solvent efficiently mediates the ortho‐C− H arylation of benzoic acids …