Progress in the catalytic reactions of CO 2 and epoxides to selectively provide cyclic or polymeric carbonates

GA Bhat, DJ Darensbourg - Green Chemistry, 2022 - pubs.rsc.org
Sustainability requires that we reuse spent carbon sources from CO2 emissions to generate
new products and materials. In this regard, carbon capture is a necessary requirement for …

[HTML][HTML] Cyclic carbonates synthesised from CO2: Applications, challenges and recent research trends

PP Pescarmona - Current Opinion in Green and Sustainable Chemistry, 2021 - Elsevier
Cyclic carbonates are a class of versatile compounds that can be prepared using the
greenhouse gas carbon dioxide as building block and that can find applications as green …

CO2-Promoted Reactions: An Emerging Concept for the Synthesis of Fine Chemicals and Pharmaceuticals

PK Sahoo, Y Zhang, S Das - ACS Catalysis, 2021 - ACS Publications
Carbon dioxide is a nontoxic and abundant chemical and has been widely used as a C1
building block for the synthesis of highly important chemicals. This greenhouse gas also has …

Mechanistic guidelines in nonreductive conversion of CO 2: the case of cyclic carbonates

F Della Monica, AW Kleij - Catalysis Science & Technology, 2020 - pubs.rsc.org
Nonreductive conversion of carbon dioxide has received wide attention in the area of
homogeneous catalysis, especially in the context of cyclic organic carbonate formation …

[HTML][HTML] Recent advances in the chemical fixation of carbon dioxide: A green route to carbonylated heterocycle synthesis

R Dalpozzo, N Della Ca', B Gabriele, R Mancuso - Catalysts, 2019 - mdpi.com
Carbon dioxide produced by human activities is one of the main contributions responsible
for the greenhouse effect, which is modifying the Earth's climate. Therefore, post-combustion …

Synthesis of Bifunctional Catalysts for the Cycloaddition of CO2 to Epoxides through an Epoxide‐Driven Strategy

S Kaewsai, S Del Gobbo, V D'Elia - ChemCatChem, 2024 - Wiley Online Library
The design of molecular scaffolds bearing multiple functional groups for the activation and
ring‐opening of epoxides is a crucial challenge for the synthesis of efficient homogeneous …

Effect of exposed active sites of semi-amorphous Fe-BTC on photocatalytic CO2 cycloaddition reaction under ambient conditions

Y He, M Xu, J **a, C Zhang, X Song, X Zhao, M Fu… - Molecular …, 2023 - Elsevier
The capture and efficient use of CO 2 is an important issue because CO 2 emissions by
burning fossil fuels is a primary cause of greenhouse effect. One of the best solutions to this …

Dinuclear chromium complexes with [OSSO]-type ligands in the copolymerization of epoxides with CO 2 and phthalic anhydride

F Niknam, A Denk, A Buonerba, B Rieger… - Catalysis Science & …, 2023 - pubs.rsc.org
In this study, a new family of dinuclear chromium complexes (1–3) containing bis-thioether-
diphenolate ligands has been introduced for the binary copolymerization of carbon dioxide …

Iron complexes for cyclic carbonate and polycarbonate formation: Selectivity control from ligand design and metal-center geometry

KA Andrea, ED Butler, TR Brown, TS Anderson… - Inorganic …, 2019 - ACS Publications
A family of 17 iron (III) aminobis (phenolate) complexes possessing different phenolate
substituents, coordination geometries, and donor arrangements were used as catalysts for …

[HTML][HTML] Metal Complexes Bearing Sulfur-Containing Ligands as Catalysts in the Reaction of CO2 with Epoxides

V Paradiso, V Capaccio, DH Lamparelli… - Catalysts, 2020 - mdpi.com
Coupling of CO2 with epoxides is a green emerging alternative for the synthesis of cyclic
organic carbonates (COC) and aliphatic polycarbonates (APC). The scope of this work is to …