Competition between halogen, hydrogen and dihydrogen bonding in brominated carboranes
Halogen bonds are a subset of noncovalent interactions with rapidly expanding applications
in materials and medicinal chemistry. While halogen bonding is well known in organic …
in materials and medicinal chemistry. While halogen bonding is well known in organic …
On the nature of the stabilisation of the E⋯ π pnicogen bond in the SbCl 3⋯ toluene complex
R Lo, P Švec, Z Růžičková, A Růžička… - Chemical …, 2016 - pubs.rsc.org
The off-symmetrical structure of the toluene⋯ SbCl3 complex is a consequence of the off-
centre location of σ-holes at the Sb atom. DFT-SAPT calculations have been used to …
centre location of σ-holes at the Sb atom. DFT-SAPT calculations have been used to …
Reassessing the Role of σ Holes in Noncovalent Interactions: It is Pauli Repulsion that Counts
MM Szczęśniak, G Chałasinski - Frontiers in Chemistry, 2022 - frontiersin.org
A number of prototypical weak electron donor–electron acceptor complexes are investigated
by the Symmetry Adapted Perturbation Theory, some of which belong to novel classes of …
by the Symmetry Adapted Perturbation Theory, some of which belong to novel classes of …
Chalcogens act as inner and outer heteroatoms in borane cages with possible consequences for σ-hole interactions
J Fanfrlík, D Hnyk - CrystEngComm, 2016 - pubs.rsc.org
Chalcogen bonds are a subset of σ-hole interactions and the number of their applications
has been increasing rapidly. While chalcogen bonding in organic compounds has been …
has been increasing rapidly. While chalcogen bonding in organic compounds has been …
Mechanism of the Asymmetric Dehydrative Allylative Cyclization of Alcohols to Cyclic Ethers Catalyzed by a CpRu Complex of the Chiral Picolinic Acid-Type Ligand …
Y Suzuki, S Iwase, M Ratanasak… - Bulletin of the …, 2021 - academic.oup.com
Abstract [Ru (II) Cp ((R)-Cl-Naph-PyCOOH)] PF6 ((R)-1) catalyzes the dehydrative
cyclization of (E)-hept-2-ene-1, 7-diol (2) to 2-vinyltetrahydro-2 H-pyran (3) with a 97: 3 S/R …
cyclization of (E)-hept-2-ene-1, 7-diol (2) to 2-vinyltetrahydro-2 H-pyran (3) with a 97: 3 S/R …
Étude en solution des interactions basées sur un trou-σ: conception, synthèse et applications de nouveaux donneurs de liaison halogène et chalcogène
R Weiss - 2021 - theses.hal.science
Ce travail de thèse s' articule autour de la synthèse de nouveaux donneurs de trous-σ, leur
étude en solution ainsi que leur mise en application en organocatalyse. Dans un premier …
étude en solution ainsi que leur mise en application en organocatalyse. Dans un premier …