Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …
with potential application in various domains of science. The key factors responsible for the …
Responsive macrocyclic and supramolecular structures powered by platinum
Humankind's manipulation of platinum dates back more than two millennia to burial objects.
Since then, its use has evolved from purely decorative purposes in jewelry to more …
Since then, its use has evolved from purely decorative purposes in jewelry to more …
Supramolecular transformation of metallacycle-linked star polymers driven by simple phosphine ligand-exchange reaction
As a common phenomenon in biological systems, supramolecular transformations of
biomacromolecules lead to specific biological functions as outputs, which thus inspire …
biomacromolecules lead to specific biological functions as outputs, which thus inspire …
Precise synthesis of concentric ring, helicoid, and ladder metallo-polymers with chevron-shaped monomers
F Su, S Zhang, Z Chen, Z Zhang, Z Li, S Lu… - Journal of the …, 2022 - ACS Publications
Molecular geometry represents one of the most important structural features and governs
physical properties and functions of materials. Nature creates a wide array of substances …
physical properties and functions of materials. Nature creates a wide array of substances …
Synthesis of platinum-containing conjugated polymers bearing chiral phosphine ligands. study of geometries and intermolecular interactions leading to aggregation
S Makino, T Horiuchi, T Ishida, N Sano, T Yajima… - …, 2022 - ACS Publications
Platinum (Pt)-containing conjugated polymers were synthesized by the dehydrochlorination
coupling polymerization of cis-and trans-dichlorobis (N-(p-(diphenylphosphino) benzoyl)-l …
coupling polymerization of cis-and trans-dichlorobis (N-(p-(diphenylphosphino) benzoyl)-l …
Chiral Amplification in π-Conjugated Helical Polymers with Circularly Polarized Luminescence
A series of d-glucose-bound optically active π-conjugated polymers (poly-Tr) were
synthesized by ternary copolymerization of 2, 5-diiodothiophene with diethynyl monomers …
synthesized by ternary copolymerization of 2, 5-diiodothiophene with diethynyl monomers …
Cationic or Neutral: Dependence of Photophysical Properties of Bis‐Alkynylphosphonium Pt (II) Complexes on Ancillary Ligand
A Paderina, A Sizova… - Chemistry–A European …, 2024 - Wiley Online Library
A series of D‐π‐A alkynylphosphonium salts with different linker between donor and
acceptor groups was used to synthesize two series of trans‐bis‐alkynylphosphonium Pt (II) …
acceptor groups was used to synthesize two series of trans‐bis‐alkynylphosphonium Pt (II) …
Chirality induction in platinum-containing polyaryleneethynylenes by exchange from achiral phosphine ligands to P-chiral phosphine ligands
R Aoki, T Horiuchi, S Makino, N Sano, Y Imai… - Polymer, 2023 - Elsevier
This study deals with chirality induction to the main chain of platinum (Pt)-containing
aryleneethynylene polymers by ligand exchange reactions. The optically inactive polymers …
aryleneethynylene polymers by ligand exchange reactions. The optically inactive polymers …
Synthesis of platinum-containing conjugated polymers bearing optically active amide groups: A mechanistic study of chiral aggregation
T Sotani, T Yajima, H Sogawa, F Sanda - Macromolecules, 2020 - ACS Publications
Chirally regulated π-conjugated polymers containing platinum (Pt) complex moieties have
great potential as chiroptically functional materials. In this study, novel platinum-containing …
great potential as chiroptically functional materials. In this study, novel platinum-containing …
Control of higher-order structures of platinum-containing conjugated polymers by ligand exchange reactions: chirality transfer from optically active ligands to optically …
T Ishida, T Sotani, N Sano, H Sogawa, F Sanda - Macromolecules, 2021 - ACS Publications
This study reports chirality transfer from optically active diphosphine ligands to optically
inactive platinum-containing polymers. Cis-platinum complex 1 smoothly reacted with …
inactive platinum-containing polymers. Cis-platinum complex 1 smoothly reacted with …