Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications

A Haque, RA Al-Balushi, IJ Al-Busaidi, MS Khan… - Chemical …, 2018 - ACS Publications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …

Responsive macrocyclic and supramolecular structures powered by platinum

MA Soto, MJ MacLachlan - Chemical Science, 2024 - pubs.rsc.org
Humankind's manipulation of platinum dates back more than two millennia to burial objects.
Since then, its use has evolved from purely decorative purposes in jewelry to more …

Supramolecular transformation of metallacycle-linked star polymers driven by simple phosphine ligand-exchange reaction

W Zheng, W Wang, ST Jiang, G Yang, Z Li… - Journal of the …, 2018 - ACS Publications
As a common phenomenon in biological systems, supramolecular transformations of
biomacromolecules lead to specific biological functions as outputs, which thus inspire …

Precise synthesis of concentric ring, helicoid, and ladder metallo-polymers with chevron-shaped monomers

F Su, S Zhang, Z Chen, Z Zhang, Z Li, S Lu… - Journal of the …, 2022 - ACS Publications
Molecular geometry represents one of the most important structural features and governs
physical properties and functions of materials. Nature creates a wide array of substances …

Synthesis of platinum-containing conjugated polymers bearing chiral phosphine ligands. study of geometries and intermolecular interactions leading to aggregation

S Makino, T Horiuchi, T Ishida, N Sano, T Yajima… - …, 2022 - ACS Publications
Platinum (Pt)-containing conjugated polymers were synthesized by the dehydrochlorination
coupling polymerization of cis-and trans-dichlorobis (N-(p-(diphenylphosphino) benzoyl)-l …

Chiral Amplification in π-Conjugated Helical Polymers with Circularly Polarized Luminescence

T Ikai, S Shimizu, S Awata, K Shinohara - Macromolecules, 2018 - ACS Publications
A series of d-glucose-bound optically active π-conjugated polymers (poly-Tr) were
synthesized by ternary copolymerization of 2, 5-diiodothiophene with diethynyl monomers …

Cationic or Neutral: Dependence of Photophysical Properties of Bis‐Alkynylphosphonium Pt (II) Complexes on Ancillary Ligand

A Paderina, A Sizova… - Chemistry–A European …, 2024 - Wiley Online Library
A series of D‐π‐A alkynylphosphonium salts with different linker between donor and
acceptor groups was used to synthesize two series of trans‐bis‐alkynylphosphonium Pt (II) …

Chirality induction in platinum-containing polyaryleneethynylenes by exchange from achiral phosphine ligands to P-chiral phosphine ligands

R Aoki, T Horiuchi, S Makino, N Sano, Y Imai… - Polymer, 2023 - Elsevier
This study deals with chirality induction to the main chain of platinum (Pt)-containing
aryleneethynylene polymers by ligand exchange reactions. The optically inactive polymers …

Synthesis of platinum-containing conjugated polymers bearing optically active amide groups: A mechanistic study of chiral aggregation

T Sotani, T Yajima, H Sogawa, F Sanda - Macromolecules, 2020 - ACS Publications
Chirally regulated π-conjugated polymers containing platinum (Pt) complex moieties have
great potential as chiroptically functional materials. In this study, novel platinum-containing …

Control of higher-order structures of platinum-containing conjugated polymers by ligand exchange reactions: chirality transfer from optically active ligands to optically …

T Ishida, T Sotani, N Sano, H Sogawa, F Sanda - Macromolecules, 2021 - ACS Publications
This study reports chirality transfer from optically active diphosphine ligands to optically
inactive platinum-containing polymers. Cis-platinum complex 1 smoothly reacted with …