Homogeneous catalysis for sustainable hydrogen storage in formic acid and alcohols

K Sordakis, C Tang, LK Vogt, H Junge… - Chemical …, 2018 - ACS Publications
Hydrogen gas is a storable form of chemical energy that could complement intermittent
renewable energy conversion. One of the main disadvantages of hydrogen gas arises from …

Homogeneous transition metal catalysis of acceptorless dehydrogenative alcohol oxidation: applications in hydrogen storage and to heterocycle synthesis

RH Crabtree - Chemical Reviews, 2017 - ACS Publications
The different types of acceptorless alcohol dehydrogenation (AAD) reactions are discussed,
followed by the catalysts and mechanisms involved. Special emphasis is put on the common …

[HTML][HTML] Homogeneously catalyzed acceptorless dehydrogenation of alcohols: A progress report

M Trincado, J Bösken, H Grützmacher - Coordination Chemistry Reviews, 2021 - Elsevier
Catalytic dehydrogenation of alcohols represents an attractive approach for future
applications as hydrogen storage systems and clean synthesis of fine chemicals. Herein, an …

Current research progress and perspectives on liquid hydrogen rich molecules in sustainable hydrogen storage

J Zheng, H Zhou, CG Wang, E Ye, JW Xu, XJ Loh… - Energy Storage …, 2021 - Elsevier
Hydrogen gas is regarded as an ideal clean energy carrier to substitute fossil-based fuels.
However, develop safe, efficient, and economical hydrogen storage approaches is still a big …

Recent Advances in Catalysis with Transition‐Metal Pincer Compounds

H Valdés, MA García‐Eleno… - …, 2018 - Wiley Online Library
Pincer complexes are useful tools for organic synthesis. Their high stability and easy
functionalization have allowed the development of novel catalytic systems that have had a …

Manganese pincer complexes for the base-free, acceptorless dehydrogenative coupling of alcohols to esters: development, scope, and understanding

DH Nguyen, X Trivelli, F Capet, JF Paul… - ACS …, 2017 - ACS Publications
Aliphatic PNP pincer-supported earth-abundant manganese (I) dicarbonyl complexes
behave as effective catalysts for the acceptorless dehydrogenative coupling of a wide range …

[HTML][HTML] Recent progress with pincer transition metal catalysts for sustainability

L Piccirilli, D Lobo Justo Pinheiro, M Nielsen - Catalysts, 2020 - mdpi.com
Our planet urgently needs sustainable solutions to alleviate the anthropogenic global
warming and climate change. Homogeneous catalysis has the potential to play a …

Acceptorless dehydrogenative coupling reactions with alcohols over heterogeneous catalysts

SMAH Siddiki, T Toyao, K Shimizu - Green Chemistry, 2018 - pubs.rsc.org
Heterogeneous catalysis for the one-pot synthesis of added-value chemicals is a growing
area in green chemistry. Among various types of organic transformations that are accessible …

Unravelling the mechanism of basic aqueous methanol dehydrogenation catalyzed by Ru–PNP pincer complexes

E Alberico, AJJ Lennox, LK Vogt, H Jiao… - Journal of the …, 2016 - ACS Publications
Ruthenium PNP complex 1a (RuH (CO) Cl (HN (C2H4P i-Pr2) 2)) represents a state-of-the-
art catalyst for low-temperature (< 100° C) aqueous methanol dehydrogenation to H2 and …

Oxidation of Organic Compounds Using Water as the Oxidant with H2 Liberation Catalyzed by Molecular Metal Complexes

S Kar, D Milstein - Accounts of chemical research, 2022 - ACS Publications
Conspectus Oxidation reactions of organic compounds play a central role in both industrial
chemical and material synthesis as well as in fine chemical and pharmaceutical synthesis …