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Metal complexes of saccharin
Metal complexes of the saccharinate anion, obtained by deprotonation of the N–H moiety of
saccharin (o-sulfobenzimide) are reviewed. A wide variety of metal species based on …
saccharin (o-sulfobenzimide) are reviewed. A wide variety of metal species based on …
Enhancement of the Magnetic Ordering Temperature and Air Stability of a Mixed Valent Vanadium Hexacyanochromate(III) Magnet to 99 °C (372 K)
Ø Hatlevik, WE Buschmann, J Zhang… - Advanced …, 1999 - Wiley Online Library
Two ambient‐temperature molecule‐based magnets (Curie temperatures Tc of∼ 350 K and
372 K) are presented, which are the result of research to identify factors in synthesis that …
372 K) are presented, which are the result of research to identify factors in synthesis that …
The saccharinate anion: a versatile and fascinating ligand in coordination chemistry
EJ Baran - Química Nova, 2005 - SciELO Brasil
The saccharinate anion, obtained by deprotonation of the NH moiety of saccharin (o-
sulfobenzimide) is a very versatile and polyfunctional ligand in coordination chemistry. In …
sulfobenzimide) is a very versatile and polyfunctional ligand in coordination chemistry. In …
First-principle investigations of nitrogen-, boron-, phosphorus-doped graphite electrodes for vanadium redox flow batteries
An issue that limits the large-scale application of vanadium redox flow batteries (VRFBs) is
their low power density, which is associated with the slow reaction kinetics of vanadium …
their low power density, which is associated with the slow reaction kinetics of vanadium …
Hexaaqua dipositive ions of the first transition series: new and accurate structures; expected and unexpected trends
In our earlier studies of Jahn-Teller active compounds of chromium (II), our desire to make
comparisons of the chromium-to-ligand bonddistances with those in other compounds, both …
comparisons of the chromium-to-ligand bonddistances with those in other compounds, both …
Synthesis of copper nanoparticles in ethylene glycol by chemical reduction with vanadium (+ 2) salts
Copper nanoparticles have been synthesized in ethylene glycol (EG) using copper sulphate
as a precursor and vanadium sulfate as an atypical reductant being active at room …
as a precursor and vanadium sulfate as an atypical reductant being active at room …
Synthesis, characterization and bioactivity of mixed-ligand Cu (II) complexes containing Schiff bases derived from S-benzyldithiocarbazate and saccharinate ligand …
TBSA Ravoof, KA Crouse, MIM Tahir, AR Cowley… - Polyhedron, 2007 - Elsevier
Mixed-ligand complexes of general formula,[Cu (NNS)(sac)](NNS′= S-benzyl-β-N-(2-
acetylpyrid-2-yl) methylenedithiocarbazate, NNS ″= S-benzyl-β-N-(2-benzoylpyrid-2-yl) …
acetylpyrid-2-yl) methylenedithiocarbazate, NNS ″= S-benzyl-β-N-(2-benzoylpyrid-2-yl) …
Structure, hydrolysis, and diffusion of aqueous vanadium ions from Car-Parrinello molecular dynamics
A molecular level understanding of the properties of electroactive vanadium species in
aqueous solution is crucial for enhancing the performance of vanadium redox flow batteries …
aqueous solution is crucial for enhancing the performance of vanadium redox flow batteries …
The solvation structure and thermodynamics of aqueous vanadium cations
The present work seeks to understand the chemical structure and solvation thermodynamics
of aqueous vanadium cations commonly employed in vanadium redox flow batteries. First …
of aqueous vanadium cations commonly employed in vanadium redox flow batteries. First …
Record antiferromagnetic coupling for a 3d/4d cyanide-bridged compound
D Pinkowicz, H Southerland, XY Wang… - Journal of the …, 2014 - ACS Publications
The pentanuclear compound [VII (tmphen) 2] 3 [MoIII (CN) 6] 2 (tmphen= 3, 4, 7, 8-
tetramethyl-1, 10-phenanthroline) exhibits a record antiferromagnetic exchange coupling …
tetramethyl-1, 10-phenanthroline) exhibits a record antiferromagnetic exchange coupling …