Metal complexes of saccharin

EJ Baran, VT Yilmaz - Coordination chemistry reviews, 2006 - Elsevier
Metal complexes of the saccharinate anion, obtained by deprotonation of the N–H moiety of
saccharin (o-sulfobenzimide) are reviewed. A wide variety of metal species based on …

Enhancement of the Magnetic Ordering Temperature and Air Stability of a Mixed Valent Vanadium Hexacyanochromate(III) Magnet to 99 °C (372 K)

Ø Hatlevik, WE Buschmann, J Zhang… - Advanced …, 1999 - Wiley Online Library
Two ambient‐temperature molecule‐based magnets (Curie temperatures Tc of∼ 350 K and
372 K) are presented, which are the result of research to identify factors in synthesis that …

The saccharinate anion: a versatile and fascinating ligand in coordination chemistry

EJ Baran - Química Nova, 2005 - SciELO Brasil
The saccharinate anion, obtained by deprotonation of the NH moiety of saccharin (o-
sulfobenzimide) is a very versatile and polyfunctional ligand in coordination chemistry. In …

First-principle investigations of nitrogen-, boron-, phosphorus-doped graphite electrodes for vanadium redox flow batteries

A Xu, L Shi, L Zeng, TS Zhao - Electrochimica Acta, 2019 - Elsevier
An issue that limits the large-scale application of vanadium redox flow batteries (VRFBs) is
their low power density, which is associated with the slow reaction kinetics of vanadium …

Hexaaqua dipositive ions of the first transition series: new and accurate structures; expected and unexpected trends

FA Cotton, LM Daniels, CA Murillo… - Inorganic …, 1993 - ACS Publications
In our earlier studies of Jahn-Teller active compounds of chromium (II), our desire to make
comparisons of the chromium-to-ligand bonddistances with those in other compounds, both …

Synthesis of copper nanoparticles in ethylene glycol by chemical reduction with vanadium (+ 2) salts

AP Reverberi, M Salerno, S Lauciello, B Fabiano - Materials, 2016 - mdpi.com
Copper nanoparticles have been synthesized in ethylene glycol (EG) using copper sulphate
as a precursor and vanadium sulfate as an atypical reductant being active at room …

Synthesis, characterization and bioactivity of mixed-ligand Cu (II) complexes containing Schiff bases derived from S-benzyldithiocarbazate and saccharinate ligand …

TBSA Ravoof, KA Crouse, MIM Tahir, AR Cowley… - Polyhedron, 2007 - Elsevier
Mixed-ligand complexes of general formula,[Cu (NNS)(sac)](NNS′= S-benzyl-β-N-(2-
acetylpyrid-2-yl) methylenedithiocarbazate, NNS ″= S-benzyl-β-N-(2-benzoylpyrid-2-yl) …

Structure, hydrolysis, and diffusion of aqueous vanadium ions from Car-Parrinello molecular dynamics

Z Jiang, K Klyukin, V Alexandrov - The journal of chemical physics, 2016 - pubs.aip.org
A molecular level understanding of the properties of electroactive vanadium species in
aqueous solution is crucial for enhancing the performance of vanadium redox flow batteries …

The solvation structure and thermodynamics of aqueous vanadium cations

F Sepehr, SJ Paddison - Chemical Physics Letters, 2013 - Elsevier
The present work seeks to understand the chemical structure and solvation thermodynamics
of aqueous vanadium cations commonly employed in vanadium redox flow batteries. First …

Record antiferromagnetic coupling for a 3d/4d cyanide-bridged compound

D Pinkowicz, H Southerland, XY Wang… - Journal of the …, 2014 - ACS Publications
The pentanuclear compound [VII (tmphen) 2] 3 [MoIII (CN) 6] 2 (tmphen= 3, 4, 7, 8-
tetramethyl-1, 10-phenanthroline) exhibits a record antiferromagnetic exchange coupling …