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Classical dynamical density functional theory: from fundamentals to applications
Classical dynamical density functional theory (DDFT) is one of the cornerstones of modern
statistical mechanics. It is an extension of the highly successful method of classical density …
statistical mechanics. It is an extension of the highly successful method of classical density …
Conductivity of concentrated electrolytes
The conductivity of ionic solutions is arguably their most important trait, being widely used in
electrochemical, biochemical, and environmental applications. The Debye-Hückel-Onsager …
electrochemical, biochemical, and environmental applications. The Debye-Hückel-Onsager …
On analytical theories for conductivity and self-diffusion in concentrated electrolytes
Describing analytically the transport properties of electrolytes, such as their conductivity or
the self-diffusion of the ions, has been a central challenge of chemical physics for almost a …
the self-diffusion of the ions, has been a central challenge of chemical physics for almost a …
Fluctuating hydrodynamics and Debye-Hückel-Onsager theory for electrolytes
We apply fluctuating hydrodynamics to strong electrolyte mixtures to compute the
concentration corrections for chemical potential, diffusivity, and conductivity. We show these …
concentration corrections for chemical potential, diffusivity, and conductivity. We show these …
Stochastic density functional theory for ions in a polar solvent
In recent years, the theoretical description of electrical noise and fluctuation-induced effects
in electrolytes has gained renewed interest, enabled by stochastic field theories like …
in electrolytes has gained renewed interest, enabled by stochastic field theories like …
Correlation decoupling of Casimir interaction in an electrolyte driven by external electric fields
It is well established that the long-range van der Waals or thermal Casimir interaction
between two semi-infinite dielectrics separated by a distance H is screened by an …
between two semi-infinite dielectrics separated by a distance H is screened by an …
Ionic fluctuations in finite volumes: fractional noise and hyperuniformity
Observing finite regions of a bigger system is a common aim, from microscopy to molecular
simulations. In the latter especially, there is ongoing interest in predicting thermodynamic …
simulations. In the latter especially, there is ongoing interest in predicting thermodynamic …
Thermopower of ionic conductors and ionic capacitors
A Würger - Physical Review Research, 2020 - APS
We theoretically study the thermoelectric response of ionic conductors to an applied
temperature gradient. As a main result, we find that open and closed systems with respect to …
temperature gradient. As a main result, we find that open and closed systems with respect to …
[HTML][HTML] Conductance of concentrated electrolytes: Multivalency and the Wien effect
The electric conductivity of ionic solutions is well understood at low ionic concentrations of
up to a few millimolar but becomes difficult to unravel at higher concentrations that are still …
up to a few millimolar but becomes difficult to unravel at higher concentrations that are still …
Electrical noise in electrolytes: a theoretical perspective
Seemingly unrelated experiments such as electrolyte transport through nanotubes, nano-
scale electrochemistry, NMR relaxometry and surface force balance measurements, all …
scale electrochemistry, NMR relaxometry and surface force balance measurements, all …