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The synthesis, properties and potential applications of cyclic polymers
Unlike their more common linear counterparts, cyclic polymers have a ring-like structure and
a lack of chain ends. Because of their topology, cyclic polymers exhibit a unique set of …
a lack of chain ends. Because of their topology, cyclic polymers exhibit a unique set of …
Ring opening polymerization of α-amino acids: advances in synthesis, architecture and applications of polypeptides and their hybrids
Polypeptides have attracted considerable attention in recent decades due to their inherent
biodegradability and tunable cytocompatibility. Macromolecular design in conjunction with …
biodegradability and tunable cytocompatibility. Macromolecular design in conjunction with …
Proton-triggered topological transformation in superbase-mediated selective polymerization enables access to ultrahigh-molar-mass cyclic polymers
The selective synthesis of ultrahigh-molar-mass (UHMM,> 2 million Da) cyclic polymers is
challenging as an exceptional degree of spatiotemporal control is required to overcome the …
challenging as an exceptional degree of spatiotemporal control is required to overcome the …
A synthetic polymer system with repeatable chemical recyclability
The development of chemically recyclable polymers offers a solution to the end-of-use issue
of polymeric materials and provides a closed-loop approach toward a circular materials …
of polymeric materials and provides a closed-loop approach toward a circular materials …
Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization of γ-butyrolactone
Ring-opening polymerization (ROP) is a powerful synthetic methodology for the chemical
synthesis of technologically important biodegradable aliphatic polyesters from cyclic esters …
synthesis of technologically important biodegradable aliphatic polyesters from cyclic esters …
Recent trends in catalytic polymerizations
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …
Their popularity has stemmed from their wide range of material properties combined with …
Polymerization of polar monomers mediated by main-group Lewis acid–base pairs
The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …
polymerization reactions or processes continues to be crucial for the synthesis of important …
Architecture-controlled ring-opening polymerization for dynamic covalent poly (disulfide) s
A strategy is reported for controlling the architecture of poly (disulfide) s by ring-opening
polymerization. Aryl thiol initiators shift the ring–chain equilibrium to yield cyclic polymers …
polymerization. Aryl thiol initiators shift the ring–chain equilibrium to yield cyclic polymers …
Update and challenges in organo-mediated polymerization reactions
Organocatalysis has become a very powerful tool for precision macromolecular chemistry,
as judged by the number of articles published in this field in the past decade. A variety of …
as judged by the number of articles published in this field in the past decade. A variety of …
Urea anions: simple, fast, and selective catalysts for ring-opening polymerizations
Aliphatic polyesters and polycarbonates are a class of biorenewable, biocompatible, and
biodegradable materials. One of the most powerful methods for accessing these materials is …
biodegradable materials. One of the most powerful methods for accessing these materials is …