Large spin-orbit coupling (SOC) is an intrinsic property of the heavy elements that directly
affects the electronic structures of the compounds. In this work, we report the synthesis and …

Supported atomic metal sites have discrete molecular orbitals. Precise control over the
energies of these sites is key to achieving novel reaction pathways with superior selectivity …

In situ X-ray absorption and emission spectroscopies (XAS and XES) are used to provide
details regarding the role of the accessibility and extent of redox activity of the Mn ions in …

The local structural changes associated with the ZIF-8 framework flexibility upon nitrogen
gas adsorption have been studied by in situ X-ray absorption spectroscopy (XAS) and high …

The preparation of MOFs including a metal with an easily exchangeable oxidation state,
while maintaining the same crystal structure and stability, is of paramount importance for …

Phase-pure magnesium ferrite (MgFe2O4) spinel nanocrystals are synthesized by a fast
microwave-assisted route. The elemental composition is optimized via the ratio of the …

Using a combination of liquid-phase experimental X-ray spectroscopy experiments and
small-scale calculations we have gained new insights into the speciation of halozincate …

Deep eutectic solvents (DES) and their hydrated mixtures are used for solvothermal routes
towards greener functional nanomaterials. Here we present the first static structural and in …

Fe-containing zeolites were studied as catalysts for the standard NH 3-SCR reaction with the
primary aim of gaining insight into the structure-function relationship of these materials …

Understanding the effects of fast neutrons on high-temperature superconductors is of
growing importance as new compact fusion reactors rely on these materials to generate the …