The discovery of the Claisen rearrangement almost a century ago1 offered a potentially
useful synthetic tool to the organic chemist. Over the decades this usefulness has been …

Lewis-acid (LA)-catalyzed reactions are of great interest because of their unique reactivities
and selectivities and mild reaction conditions used. 1, 2 A wide variety of reactions using …

The para‐Claisen rearrangement of aryl 1‐propargyl ethers involves two‐step [3, 3]‐
sigmatropic rearrangements and dearomatization process, which has high activation …

Since its discovery in 1912, 1 the Claisen rearrangement has become one of the most
widely used synthetic tools for the organic chemist. For synthetic purposes, the Claisen …

Enantioselective intra-and intermolecular insertions of aromatic sulfamate esters into
activated C–H bonds have been achieved via in situ generated phenyliodinanes in the …

A highly diastereoselective, microwave-induced Claisen rearrangement of an appropriately
substituted propargylic enol ether allows the formation of the sterically congested C8− C14 …

Iridium(III)-catalyzed tandem Claisen rearrangement–intramolecular hydroaryloxylation of
aryl allyl ethers to form dihydrobenzofurans - ScienceDirect Skip to main contentSkip to …

The microwave-accelerated Claisen rearrangement of allyl aryl ethers was investigated, in
order to gain insight into the scope of the catalysts, solvents, temperatures, and substrates …

The first total syntheses of hericenones C–H and “putative 3-hydroxyhericenone F” were
achieved. Highlights of the synthesis include the straightforward construction of the …

The addition of stoichiometric quantities of water accelerates both the trimethylaluminum-
mediated aromatic Claisen reaction and the chiral zirconocene-catalyzed asymmetric …