This review comprehensively covers the coordination chemistry of elemental phosphorus
during the years 2011–2020. The main part is dedicated to the activation of white …

For several decades, academic researchers have been intensively studying the chemistry of
white phosphorus (P4) in the hope of develo** direct methods for its transformation into …

The main feedstock for the value-added phosphorus chemicals used in industry and
research is white phosphorus (P4), from which the key intermediate for forming P (III) …

Develo** practical and mild strategies for the direct functionalization of white phosphorus
(P4) without chlorination is an appealing but formidable challenge. To this end, we report a …

Dialkyl phosphites (DAPIs) are important precursors in the formation of phosphorus–carbon
and phosphorus–heteroatom bonds with significant industrial applications. Traditional PCl3 …

The complexes containing cyclo-P n ligands which are π-coordinated to a metal atom have
been known since the late 1970 s. Cyclo-P n ligands being cyclic aromatic P-donors …

White phosphorus activation with low-valent metal species has proved to be very effective in
converting P4 into small P n-containing molecules with n≤ 4. Much less developed are …

Abstract Detailed 31P {1H} NMR spectroscopic investigations provide deeper insight into the
complex, multi‐step mechanisms involved in the recently reported photocatalytic arylation of …

Diazoalkenes readily react with tert‐butylphosphaalkyne (tBuCP) and white phosphorus
(P4) to afford novel phosphorus heterocycles, 3H‐1, 2, 4‐diazamonophospholes and 1, 2, 3 …

This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …