Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013‏ - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

When metal clusters meet carbon cages: endohedral clusterfullerenes

S Yang, T Wei, F ** - Chemical society reviews, 2017‏ - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

[ספר][B] Organic electrochemistry

O Hammerich, B Speiser - 2016‏ - api.taylorfrancis.com
Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

Chemical, electrochemical, and structural properties of endohedral metallofullerenes

MN Chaur, F Melin, AL Ortiz… - Angewandte Chemie …, 2009‏ - Wiley Online Library
Ever since the first experimental evidence of the existence of endohedral metallofullerenes
(EMFs) was obtained, the search for carbon cages with encapsulated metals and small …

Bonding in endohedral metallofullerenes as studied by quantum theory of atoms in molecules

AA Popov, L Dunsch - Chemistry–A European Journal, 2009‏ - Wiley Online Library
Metal–cage and intracluster bonding was studied in detail by quantum theory of atoms in
molecules (QTAIM) for the four major classes of endohedral metallofullerenes (EMFs) …

Fullerenes encaging metal clusters—clusterfullerenes

S Yang, F Liu, C Chen, M Jiao, T Wei - Chemical Communications, 2011‏ - pubs.rsc.org
Clusterfullerenes represent a novel branch of endohedral fullerenes, which are
characterized by a robust fullerene cage with metal clusters encaged in its hollow. Since the …

Fullerene derivatives as nano-additives in polymer composites

AV Penkova, SFA Acquah, LB Piotrovskiy… - Russian Chemical …, 2017‏ - iopscience.iop.org
Since their discovery, fullerenes have become one of the most recognizable molecules in
science. The'beautiful molecule'described by Harold W. Kroto has been subtly referenced in …

Yb@C2n (n = 40, 41, 42): New Fullerene Allotropes with Unexplored Electrochemical Properties

X Lu, Z Slanina, T Akasaka, T Tsuchiya… - Journal of the …, 2010‏ - ACS Publications
A series of13C-enriched monoytterbium endohedral metallofullerenes (EMFs) Yb@ C2 n
(n= 40, 41, 42) was synthesized and isolated. Their cage structures were systematically …

Beyond the Butterfly: Sc2C2@C2v(9)-C86, an Endohedral Fullerene Containing a Planar, Twisted Sc2C2 Unit with Remarkable Crystalline Order in an …

CH Chen, KB Ghiassi, MR Cerón… - Journal of the …, 2015‏ - ACS Publications
The synthesis, isolation, and characterization of a new endohedral fullerene, Sc2C88, is
reported. Characterization by single crystal X-ray diffraction revealed that it is the carbide …

A Pseudoatom in a Cage: Trimetallofullerene Y3@C80 Mimics Y3N@C80 with Nitrogen Substituted by a Pseudoatom

AA Popov, L Zhang, L Dunsch - Acs Nano, 2010‏ - ACS Publications
Y3C80 obtained in the synthesis of nitride clusterfullerenes Y3N@ C2 n (2 n= 80− 88) by the
reactive atmosphere method is found to be a genuine trimetallofullerene, Y3@ C80, with low …