Density functional theory for transition metals and transition metal chemistry

CJ Cramer, DG Truhlar - Physical Chemistry Chemical Physics, 2009‏ - pubs.rsc.org
We introduce density functional theory and review recent progress in its application to
transition metal chemistry. Topics covered include local, meta, hybrid, hybrid meta, and …

Magnetic interactions in molecules and highly correlated materials: physical content, analytical derivation, and rigorous extraction of magnetic Hamiltonians

JP Malrieu, R Caballol, CJ Calzado, C De Graaf… - Chemical …, 2014‏ - ACS Publications
Magnetism is a phenomenon that has always captured the imagination of humans. Its
discovery in the western world is attributed to the ancient Greek civilization. More than 2500 …

Prediction of molecular properties and molecular spectroscopy with density functional theory: From fundamental theory to exchange-coupling

F Neese - Coordination Chemistry Reviews, 2009‏ - Elsevier
This review provides a detailed account of density functional theory (DFT) and its application
to the calculation of molecular properties of inorganic compounds. After introducing some …

Nature of the Fe−O2 Bonding in Oxy-Myoglobin: Effect of the Protein

H Chen, M Ikeda-Saito, S Shaik - Journal of the American …, 2008‏ - ACS Publications
The nature of the Fe− O2 bonding in oxy-myoglobin was probed by theoretical
calculations:(a) QM/MM (hybrid quantum mechanical/molecular mechanical) calculations …

Consistent descriptions of metal–ligand bonds and spin-crossover in inorganic chemistry

KP Kepp - Coordination Chemistry Reviews, 2013‏ - Elsevier
Density functional theory (DFT) is today the unchallenged tool for routinely obtaining
molecular information on chemical stability, reactivity, and electronic structure across the …

Self-interaction corrections in density functional theory

T Tsuneda, K Hirao - The Journal of chemical physics, 2014‏ - pubs.aip.org
Self-interaction corrections for Kohn-Sham density functional theory are reviewed for their
physical meanings, formulations, and applications. The self-interaction corrections get rid of …

[PDF][PDF] First heterotrimetallic {3d-4d-4f} single chain magnet, constructed from anisotropic high-spin heterometallic nodes and paramagnetic spacers

D Visinescu, AM Madalan, M Andruh, C Duhayon… - Chem.-Eur. J, 2009‏ - ungur.org
Polymetallic complexes are more and more involved in materials science. The metal ions
exert a functional role, carrying magnetic, optical, or redox properties, and a structural one …

Structural and electronic effects on the exchange interactions in dinuclear bis (phenoxo)-bridged copper (II) complexes

D Venegas-Yazigi, D Aravena, E Spodine… - Coordination Chemistry …, 2010‏ - Elsevier
Computational methods based on density functional theory have been employed to analyze
the magnetic properties of dinuclear bis (phenoxo)-bridged CuII complexes. While the …

Can large magnetic anisotropy and high spin really coexist?

E Ruiz, J Cirera, J Cano, S Alvarez, C Loose… - Chemical …, 2008‏ - pubs.rsc.org
Can large magnetic anisotropy and high spin really coexist? - Chemical Communications (RSC
Publishing) DOI:10.1039/B714715E Royal Society of Chemistry View PDF VersionPrevious …

Family of Carboxylate- and Nitrate-diphenoxo Triply Bridged Dinuclear NiIILnIII Complexes (Ln = Eu, Gd, Tb, Ho, Er, Y): Synthesis, Experimental and Theoretical …

E Colacio, J Ruiz, AJ Mota, MA Palacios… - Inorganic …, 2012‏ - ACS Publications
Seven acetate-diphenoxo triply bridged MII-LnIII complexes (MII= NiII and LnIII= Gd, Tb, Ho,
Er, and Y; MII= ZnII and LnIII= HoIII and ErIII) of formula [M (μ-L)(μ-OAc) Ln (NO3) 2], one …