The dynamic translocation of a metal catalyst along an alkyl side chain—often coined as
'chain-walking'—has opened new retrosynthetic possibilities that enable functionalization at …

The carboxylation of readily available organo halides with CO 2 represents a practical
strategy to afford valuable carboxylic acids. However, efficient carboxylation of inexpensive …

A family of 4, 4′-t Bu2-2, 2′-bipyridine (t Bubpy) ligands with substituents in either the 6-
position, 4, 4′-t Bu2-6-Me-bpy (t BubpyMe), or 6 and 6′-positions, 4, 4′-t Bu2-6, 6′-R2 …

Transition metal-catalyzed reductive cross-couplings to build C–C/Si bonds have been
developed, but the reductive cross-coupling to create the C (sp2)–B bond has not been …

An electroreductive deoxygenative carboxylation of alkyl oxalates with CO2 is demonstrated
for the first time, which offers a general and scalable method for obtaining various carboxylic …

The synthetic insertion of carbon dioxide into organic scaffolds typically requires the reaction
of CO2 with a carbanion (carboxylation step), with the latter being generated through …

Herein, we report a synergistic photoredox/palladium catalytic system for the efficient
enantioconvergent synthesis of axially chiral esters from racemic heterobiaryl (pseudo) …

The catalytic regio-and enantioselective hydrocarboxylation of alkenes with carbon dioxide
is a straightforward strategy to construct enantioenriched α-chiral carboxylic acids but …

A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with
CO2 has been accomplished, furnishing a variety of benzosultam-containing acrylates in …

Herein, visible light-induced, nickel-catalyzed direct functionalization of the Hantzsch esters
(HEs) with readily accessible alkyl bromides has been successfully achieved by taking …