Site-selective arylation of carboxamides from unprotected peptides
W Li, Y Chen, Y Chen, S **a, W Chang… - Journal of the …, 2023 - ACS Publications
The amidated peptides are an important class of biologically active compounds due to their
unique biological properties and wide applications as potential peptide drugs and …
unique biological properties and wide applications as potential peptide drugs and …
DFT-Enabled Development of Hemilabile (P∧N) Ligands for Gold(I/III) RedOx Catalysis: Application to the Thiotosylation of Aryl Iodides
Ligand-enabled oxidative addition of Csp2-X bonds to Au (I) centers has recently appeared
as a valuable strategy for the development of catalytic RedOx processes. Several cross …
as a valuable strategy for the development of catalytic RedOx processes. Several cross …
Ligand-Enabled Gold-Catalyzed C(sp2)–O Cross-Coupling Reactions
Reported herein is a ligand-enabled gold-catalyzed C (sp2)–O cross-coupling reaction of
aryl iodides and aliphatic alcohols. The synthesis of a variety of aryl alkyl ethers including …
aryl iodides and aliphatic alcohols. The synthesis of a variety of aryl alkyl ethers including …
Unlocking the Chain‐Walking Process in Gold Catalysis
The successful realization of gold‐catalyzed chain‐walking reactions, facilitated by ligand‐
enabled Au (I)/Au (III) redox catalysis, has been reported for the first time. This breakthrough …
enabled Au (I)/Au (III) redox catalysis, has been reported for the first time. This breakthrough …
Ligand‐Enabled Gold‐Catalyzed Cyanation of Organohalides
Herein, we disclose the first report on gold‐catalyzed C (sp2)‐CN cross‐coupling reaction
by employing a ligand‐enabled Au (I)/Au (III) redox catalysis. This transformation utilizes …
by employing a ligand‐enabled Au (I)/Au (III) redox catalysis. This transformation utilizes …
Gold–manganese bimetallic redox coupling with light
S **a, W Li, H Chen, C Zhu, J Han… - Journal of the American …, 2023 - ACS Publications
The classical Au (I)/Au (III) redox couple chemistry has been limited to constructing C–C and
C–X bonds, and thus, the exploration of the elementary reaction of gold redox coupling is …
C–X bonds, and thus, the exploration of the elementary reaction of gold redox coupling is …
Hemilabile P, N-ligand-assisted gold-catalyzed Heck reaction of aryl and styryl iodides with styrenes
C Wei, L Zhang, Z **a - Organic Letters, 2023 - ACS Publications
A gold-catalyzed Heck reaction of aryl and styryl iodides with styrenes was developed. The
hemilabile P, N-ligand-assisted gold-catalyzed C (sp2)–C (sp2) cross-coupling can …
hemilabile P, N-ligand-assisted gold-catalyzed C (sp2)–C (sp2) cross-coupling can …
Photosensitized Reductive Elimination of Gold (III) to Enable Esterification of Aryl Iodides with Carboxylic Acids
J Wu, W Du, L Zhang, G Li, R Yang, Z **a - JACS Au, 2024 - ACS Publications
Compared to the well-established transition metal-catalyzed cross-coupling reactions, Au
(I)/Au (III)-catalyzed cross-coupling reactions have lagged behind. Despite some …
(I)/Au (III)-catalyzed cross-coupling reactions have lagged behind. Despite some …
Consolidation of the Oxidant‐Free Au (I)/Au (III) Catalysis Enabled by the Hemilabile Ligand Strategy
In this minireview we survey the challenges and strategies in gold redox catalysis. Gold's
reluctance to oxidative addition reactions due to its high redox potential limits its …
reluctance to oxidative addition reactions due to its high redox potential limits its …
Gold‐Catalyzed Heck and Suzuki‐Type Reactions: Challenges and Recent Advances
J Wu, W Du, L Zhang, G Li, Z **a - European Journal of Organic …, 2024 - Wiley Online Library
Transition metal‐catalyzed Suzuki and Heck reactions are two of the most common carbon‐
carbon bond formation reactions. Gold, unlike other transition metals (Pd, Ni, and Cu), offers …
carbon bond formation reactions. Gold, unlike other transition metals (Pd, Ni, and Cu), offers …