Stable N‐Heterocyclic Carbene Adducts of Arylchlorosilylenes and Their Germanium Homologues
AC Filippou, O Chernov, B Blom… - … A European Journal, 2010 - Wiley Online Library
The first N‐heterocyclic carbene adducts of arylchlorosilylenes are reported and compared
with the homologous germanium compounds. The arylsilicon (II) chlorides SiArCl (Im‐Me4) …
with the homologous germanium compounds. The arylsilicon (II) chlorides SiArCl (Im‐Me4) …
Metal Activation of a Germylenoid, a New Approach to Metal–Germanium Triple Bonds: Synthesis and Reactions of the Germylidyne Complexes [Cp (CO) 2M Ge–C …
AC Filippou, KW Stumpf, O Chernov… - …, 2012 - ACS Publications
The reactions of the germylenoid Li (THF) 3GeCl2C (SiMe3) 3 with the carbonyl metalates Li
[CpMo (CO) 3] and K [CpW (CO) 3](Cp= η5-C5H5) in toluene afford selectively the …
[CpMo (CO) 3] and K [CpW (CO) 3](Cp= η5-C5H5) in toluene afford selectively the …
Coordination Chemistry of [E(Idipp)]2+ Ligands (E = Ge, Sn): Metal Germylidyne [Cp*(CO)2WGe(Idipp)]+ and Metallotetrylene [Cp*(CO)3W–E(Idipp)]+ Cations
YN Lebedev, U Das, G Schnakenburg… - …, 2017 - ACS Publications
The synthesis and full characterization of the NHC-stabilized tungstenochlorostannylene
[Cp*(CO) 3W–SnCl (Idipp)](1Sn), the NHC-stabilized chlorogermylidyne complex [Cp*(CO) …
[Cp*(CO) 3W–SnCl (Idipp)](1Sn), the NHC-stabilized chlorogermylidyne complex [Cp*(CO) …
Computational design of direct-bandgap semiconductors that lattice-match silicon
Crystalline silicon is an indirect-bandgap semiconductor, making it an inefficient emitter of
light. The successful integration of silicon-based electronics with optical components will …
light. The successful integration of silicon-based electronics with optical components will …
Growth of tin-free germanium carbon alloys using carbon tetrabromide (CBr4)
Direct bandgap group IV materials could provide intimate integration of lasers, amplifiers,
and compact modulators within complementary metal–oxide–semiconductor for smaller …
and compact modulators within complementary metal–oxide–semiconductor for smaller …
Platinum Complexes Containing Pyramidalized Germanium and Tin Dihalide Ligands Bound through σ, σ M E Multiple Bonds
F Hupp, M Ma, F Kroll… - … A European Journal, 2014 - Wiley Online Library
We present the isolation of the first mononuclear dihalogermylene, and mono‐and dinuclear
stannylene complexes of transition metals. These exhibit exceptionally pyramidalized Group …
stannylene complexes of transition metals. These exhibit exceptionally pyramidalized Group …
[HTML][HTML] Band structure of germanium carbides for direct bandgap silicon photonics
CA Stephenson, WA O'Brien, MW Penninger… - Journal of Applied …, 2016 - pubs.aip.org
Compact optical interconnects require efficient lasers and modulators compatible with
silicon. Ab initio modeling of Ge 1− x C x (x= 0.78%) using density functional theory with …
silicon. Ab initio modeling of Ge 1− x C x (x= 0.78%) using density functional theory with …
Novel Si(II)+ and Ge(II)+ Compounds as Efficient Catalysts in Organosilicon Chemistry: Siloxane Coupling Reaction†
E Fritz-Langhals, S Werge, S Kneissl… - … Process Research & …, 2020 - ACS Publications
Novel catalytically active cationic Si (II) and Ge (II) compounds were synthesized and
isolated in pure form. The Ge (II)+-based compounds proved to be stable against air and …
isolated in pure form. The Ge (II)+-based compounds proved to be stable against air and …
1, 2-Dihalodigermenes bearing bulky Eind groups: synthesis, characterization, and conversion to halogermylenoids
N Hayakawa, T Sugahara, Y Numata, H Kawaai… - Dalton …, 2018 - pubs.rsc.org
1, 2-Dihalodigermenes,(E)-(Eind) XGeGeX (Eind)(X= Br and Cl), bearing the fused-ring
bulky Eind group (Eind= 1, 1, 3, 3, 5, 5, 7, 7-octaethyl-s-hydrindacen-4-yl) have been …
bulky Eind group (Eind= 1, 1, 3, 3, 5, 5, 7, 7-octaethyl-s-hydrindacen-4-yl) have been …
Preparation, Structure, and 73Ge NMR Spectroscopy of Arylgermanes ArGeH3, Ar2GeH2, and Ar3GeH
F Riedmiller, GL Wegner, A Jockisch… - …, 1999 - ACS Publications
Arylgermanes of the types ArGeH3, Ar2GeH2, and Ar3GeH are important precursors for the
preparation of oligo-and polygermanes. These precursors are readily prepared in good …
preparation of oligo-and polygermanes. These precursors are readily prepared in good …