Molecular chromophore–catalyst assemblies for solar fuel applications

DL Ashford, MK Gish, AK Vannucci… - Chemical …, 2015 - ACS Publications
As the world's population increases, the US Department of Energy has estimated that energy
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …

O–O bond formation in ruthenium-catalyzed water oxidation: single-site nucleophilic attack vs. O–O radical coupling

DW Shaffer, Y **e, JJ Concepcion - Chemical Society Reviews, 2017 - pubs.rsc.org
In this review we discuss at the mechanistic level the different steps involved in water
oxidation catalysis with ruthenium-based molecular catalysts. We have chosen to focus on …

Finding the way to solar fuels with dye-sensitized photoelectrosynthesis cells

MK Brennaman, RJ Dillon, L Alibabaei… - Journal of the …, 2016 - ACS Publications
The dye-sensitized photoelectrosynthesis cell (DSPEC) integrates high bandgap,
nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of …

Binary molecular-semiconductor p–n junctions for photoelectrocatalytic CO2 reduction

B Shan, S Vanka, TT Li, L Troian-Gautier… - Nature Energy, 2019 - nature.com
In one approach to solar energy conversion, light-harvesting sensitizers absorb and convert
photons into electron–hole pairs to drive water splitting or CO2 reduction to produce fuels …

Artificial photosynthesis: Where are we now? Where can we go?

RL House, NYM Iha, RL Coppo, L Alibabaei… - … of Photochemistry and …, 2015 - Elsevier
Widespread implementation of renewable energy technologies, while preventing significant
increases in greenhouse gas emissions, appears to be the only viable solution to meeting …

Recent advances in dye-sensitized photoelectrochemical cells for water splitting

S Zhang, H Ye, J Hua, H Tian - EnergyChem, 2019 - Elsevier
Dye-sensitized photoelectrochemical cells (DSPECs) that can drive water splitting to
generate solar fuel through the absorption of sun light, has attracted growing interest in the …

Recent advances in metal-free photosensitizers for dye-sensitized photoelectrochemical cells

XL Wang, JF Huang, JM Liu, P Tsiakaras - Coordination Chemistry Reviews, 2025 - Elsevier
Dye-sensitized photoelectrochemical cells (DSPECs), which consist an effective approach to
achieve total water splitting, have attracted a lot of attention in recent years. Nowadays, most …

Visible light-driven water oxidation using a covalently-linked molecular catalyst–sensitizer dyad assembled on a TiO 2 electrode

M Yamamoto, L Wang, F Li, T Fukushima, K Tanaka… - Chemical …, 2016 - pubs.rsc.org
The combination of porphyrin as a sensitizer and a ruthenium complex as a water oxidation
catalyst (WOC) is promising to exploit highly efficient molecular artificial photosynthetic …

Photoelectrochemical cells with a pyridine-anchored bilayer photoanode for water splitting

K Tang, JY Shao, Y Yan, YW Zhong - Langmuir, 2024 - ACS Publications
A dye-sensitized photoanode is prepared by coassembling a Ru complex photosensitizer
and a Ru water oxidation catalyst (WOC) on a TiO2 substrate, in which the WOC molecules …

Self-assembled molecular p/n junctions for applications in dye-sensitized solar energy conversion

BH Farnum, KR Wee, TJ Meyer - Nature Chemistry, 2016 - nature.com
The achievement of long-lived photoinduced redox separation lifetimes has long been a
central goal of molecular-based solar energy conversion strategies. The longer the redox …