3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Metalla-electrocatalyzed C–H activation by earth-abundant 3d metals and beyond

L Ackermann - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus To improve the efficacy of molecular syntheses, researchers wish to capitalize
upon the selective modification of otherwise inert C–H bonds. The past two decades have …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Transient directing groups for transformative C–H activation by synergistic metal catalysis

P Gandeepan, L Ackermann - Chem, 2018 - cell.com
The development of methods for the functionalization of otherwise inert C–H bonds is one of
the major foci in molecular syntheses. Recent advances have significantly improved the …

Decoding directing groups and their pivotal role in C− H activation

K Murali, LA Machado, RL Carvalho… - … A European Journal, 2021 - Wiley Online Library
Synthetic organic chemistry has witnessed a plethora of functionalization and
defunctionalization strategies. In this regard, C− H functionalization has been at the forefront …

Green strategies for transition metal-catalyzed C–H activation in molecular syntheses

U Dhawa, N Kaplaneris, L Ackermann - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Transition metal catalyzed C–H activation has surfaced as a powerful tool to improve the
efficacy of molecular synthesis. Last two decades have witnessed a considerable progress …

Direct functionalization of C− H bonds by iron, nickel, and cobalt catalysis

G Pototschnig, N Maulide… - Chemistry–A European …, 2017 - Wiley Online Library
Non‐precious‐metal‐catalyzed reactions are of increasing importance in chemistry due to
the outstanding ecological and economic properties of these metals. In the subfield of metal …

Chelation-assisted nickel-catalyzed C− H functionalizations

SM Khake, N Chatani - Trends in Chemistry, 2019 - cell.com
Use of a directing group in C–H functionalizations, often referred to as chelation assistance,
is one of the most reliable methods for achieving highly efficient and highly site-selective …

Overcoming the Limitations of C− H Activation with Strongly Coordinating N‐Heterocycles by Cobalt Catalysis

H Wang, MM Lorion… - Angewandte Chemie …, 2016 - Wiley Online Library
Strongly coordinating nitrogen heterocycles, including pyrimidines, oxazolines, pyrazoles,
and pyridines, were fully tolerated in cobalt‐catalyzed C− H amidations by imidate …

Expedient C–H chalcogenation of indolines and indoles by positional-selective copper catalysis

P Gandeepan, J Koeller, L Ackermann - ACS Catalysis, 2017 - ACS Publications
A versatile protocol for the C–H chalcogenation of indolines and indoles by means of copper
catalysis was established. The C–H functionalization occurred selectively at the C7 position …