3d transition metals for C–H activation
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …
notable applications to material sciences, crop protection, drug discovery, and …
Metalla-electrocatalyzed C–H activation by earth-abundant 3d metals and beyond
L Ackermann - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus To improve the efficacy of molecular syntheses, researchers wish to capitalize
upon the selective modification of otherwise inert C–H bonds. The past two decades have …
upon the selective modification of otherwise inert C–H bonds. The past two decades have …
[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry
C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
Transient directing groups for transformative C–H activation by synergistic metal catalysis
The development of methods for the functionalization of otherwise inert C–H bonds is one of
the major foci in molecular syntheses. Recent advances have significantly improved the …
the major foci in molecular syntheses. Recent advances have significantly improved the …
Decoding directing groups and their pivotal role in C− H activation
K Murali, LA Machado, RL Carvalho… - … A European Journal, 2021 - Wiley Online Library
Synthetic organic chemistry has witnessed a plethora of functionalization and
defunctionalization strategies. In this regard, C− H functionalization has been at the forefront …
defunctionalization strategies. In this regard, C− H functionalization has been at the forefront …
Green strategies for transition metal-catalyzed C–H activation in molecular syntheses
Transition metal catalyzed C–H activation has surfaced as a powerful tool to improve the
efficacy of molecular synthesis. Last two decades have witnessed a considerable progress …
efficacy of molecular synthesis. Last two decades have witnessed a considerable progress …
Direct functionalization of C− H bonds by iron, nickel, and cobalt catalysis
G Pototschnig, N Maulide… - Chemistry–A European …, 2017 - Wiley Online Library
Non‐precious‐metal‐catalyzed reactions are of increasing importance in chemistry due to
the outstanding ecological and economic properties of these metals. In the subfield of metal …
the outstanding ecological and economic properties of these metals. In the subfield of metal …
Chelation-assisted nickel-catalyzed C− H functionalizations
SM Khake, N Chatani - Trends in Chemistry, 2019 - cell.com
Use of a directing group in C–H functionalizations, often referred to as chelation assistance,
is one of the most reliable methods for achieving highly efficient and highly site-selective …
is one of the most reliable methods for achieving highly efficient and highly site-selective …
Overcoming the Limitations of C− H Activation with Strongly Coordinating N‐Heterocycles by Cobalt Catalysis
Strongly coordinating nitrogen heterocycles, including pyrimidines, oxazolines, pyrazoles,
and pyridines, were fully tolerated in cobalt‐catalyzed C− H amidations by imidate …
and pyridines, were fully tolerated in cobalt‐catalyzed C− H amidations by imidate …
Expedient C–H chalcogenation of indolines and indoles by positional-selective copper catalysis
A versatile protocol for the C–H chalcogenation of indolines and indoles by means of copper
catalysis was established. The C–H functionalization occurred selectively at the C7 position …
catalysis was established. The C–H functionalization occurred selectively at the C7 position …