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Metal-catalysed C–H bond activation and borylation
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …
received a remarkable level of attention as a popular reaction in the synthesis of …
First-row d-block element-catalyzed carbon–boron bond formation and related processes
SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
Methodologies and strategies for selective borylation of C–Het and C–C bonds
M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
Metal-catalyzed Markovnikov-type selective hydrofunctionalization of terminal alkynes
J Chen, WT Wei, Z Li, Z Lu - Chemical Society Reviews, 2024 - pubs.rsc.org
Metal-catalyzed highly Markovnikov-type selective hydrofunctionalization of terminal alkynes
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …
Photoinduced borylation for the synthesis of organoboron compounds: focus review
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …
transformations. The development of practical and convenient ways to synthesize boronate …
Tetracoordinate boron intermediates enable unconventional transformations
K Yang, Q Song - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Organoboron compounds are a class of multifunctional reagents for the
construction of carbon–carbon and carbon–heteroatom bonds in modern synthetic …
construction of carbon–carbon and carbon–heteroatom bonds in modern synthetic …
Diversity-oriented synthesis of P-stereogenic and axially chiral monodentate biaryl phosphines enabled by CP bond cleavage
L Pang, Z Huang, Q Sun, G Li, J Liu, B Li, C Ma… - Nature …, 2023 - nature.com
Chiral monodentate biaryl phosphines (MOPs) have attracted intense attention as chiral
ligands over the past decades. However, the creation of structurally diverse chiral MOPs with …
ligands over the past decades. However, the creation of structurally diverse chiral MOPs with …
[HTML][HTML] Activation of the Si–B interelement bond related to catalysis
Si–B reagents, namely silylboronic esters and silylboranes, have become increasingly
attractive as versatile reagents to introduce silicon and boron atoms into organic …
attractive as versatile reagents to introduce silicon and boron atoms into organic …
Selective C− N borylation of alkyl amines promoted by Lewis base
J Hu, G Wang, S Li, Z Shi - Angewandte Chemie International …, 2018 - Wiley Online Library
An efficient method for the metal‐free deaminative borylation of alkylamines, using bis
(catecholato) diboron as the boron source, to directly synthesize various alkyl potassium …
(catecholato) diboron as the boron source, to directly synthesize various alkyl potassium …
Protodeboronation of (hetero) arylboronic esters: direct versus prehydrolytic pathways and self-/auto-catalysis
HLD Hayes, R Wei, M Assante… - Journal of the …, 2021 - ACS Publications
The kinetics and mechanism of the base-catalyzed hydrolysis (ArB (OR) 2→ ArB (OH) 2) and
protodeboronation (ArB (OR) 2→ ArH) of a series of boronic esters, encompassing eight …
protodeboronation (ArB (OR) 2→ ArH) of a series of boronic esters, encompassing eight …