Metal-catalysed C–H bond activation and borylation

R Bisht, C Haldar, MMM Hassan, ME Hoque… - Chemical Society …, 2022 - pubs.rsc.org
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Methodologies and strategies for selective borylation of C–Het and C–C bonds

M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Metal-catalyzed Markovnikov-type selective hydrofunctionalization of terminal alkynes

J Chen, WT Wei, Z Li, Z Lu - Chemical Society Reviews, 2024 - pubs.rsc.org
Metal-catalyzed highly Markovnikov-type selective hydrofunctionalization of terminal alkynes
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …

Photoinduced borylation for the synthesis of organoboron compounds: focus review

YM Tian, XN Guo, H Braunschweig, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

Tetracoordinate boron intermediates enable unconventional transformations

K Yang, Q Song - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Organoboron compounds are a class of multifunctional reagents for the
construction of carbon–carbon and carbon–heteroatom bonds in modern synthetic …

Diversity-oriented synthesis of P-stereogenic and axially chiral monodentate biaryl phosphines enabled by CP bond cleavage

L Pang, Z Huang, Q Sun, G Li, J Liu, B Li, C Ma… - Nature …, 2023 - nature.com
Chiral monodentate biaryl phosphines (MOPs) have attracted intense attention as chiral
ligands over the past decades. However, the creation of structurally diverse chiral MOPs with …

[HTML][HTML] Activation of the Si–B interelement bond related to catalysis

JJ Feng, W Mao, L Zhang, M Oestreich - Chemical Society Reviews, 2021 - pubs.rsc.org
Si–B reagents, namely silylboronic esters and silylboranes, have become increasingly
attractive as versatile reagents to introduce silicon and boron atoms into organic …

Selective C− N borylation of alkyl amines promoted by Lewis base

J Hu, G Wang, S Li, Z Shi - Angewandte Chemie International …, 2018 - Wiley Online Library
An efficient method for the metal‐free deaminative borylation of alkylamines, using bis
(catecholato) diboron as the boron source, to directly synthesize various alkyl potassium …

Protodeboronation of (hetero) arylboronic esters: direct versus prehydrolytic pathways and self-/auto-catalysis

HLD Hayes, R Wei, M Assante… - Journal of the …, 2021 - ACS Publications
The kinetics and mechanism of the base-catalyzed hydrolysis (ArB (OR) 2→ ArB (OH) 2) and
protodeboronation (ArB (OR) 2→ ArH) of a series of boronic esters, encompassing eight …