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The impact of boron hybridisation on photocatalytic processes
A Marotta, CE Adams, JJ Molloy - … Chemie International Edition, 2022 - Wiley Online Library
Recently the fruitful merger of organoboron chemistry and photocatalysis has come to the
forefront of organic synthesis, resulting in the development of new technologies to access …
forefront of organic synthesis, resulting in the development of new technologies to access …
Synthesis of polysubstituted 2-oxabicyclo [2.1. 1] hexanes via visible-light-induced energy transfer
Y Liang, R Kleinmans, CG Daniliuc… - Journal of the American …, 2022 - ACS Publications
Synthesis of bicyclic scaffolds has attracted growing interest because they are of high
importance in modern pharmaceutical development. Here we report a strategy to access …
importance in modern pharmaceutical development. Here we report a strategy to access …
The current utility and future potential of multiborylated alkanes
Organoboron chemistry has become a cornerstone of modern synthetic methodology. Most
of these reactions use an organoboron starting material that contains just one C (sp 2)–B or …
of these reactions use an organoboron starting material that contains just one C (sp 2)–B or …
Double strain-release [2π+ 2σ]-photocycloaddition
In pursuit of potent pharmaceutical candidates and to further improve their chemical traits,
small ring systems can serve as a potential starting point. Small ring units have the …
small ring systems can serve as a potential starting point. Small ring units have the …
Synthesis of borylated carbocycles by [2+ 2]-cycloadditions and photo-ene reactions
Saturated bicyclic compounds make up a valuable class of building blocks in the
development of agrochemicals and pharmaceuticals. Here, we present the synthesis of …
development of agrochemicals and pharmaceuticals. Here, we present the synthesis of …
Visible-light-mediated energy transfer enables cyclopropanes bearing contiguous all-carbon quaternary centers
D **a, R Wu, J Wang, X Han, Y Li, Q Li, X Luan… - ACS …, 2023 - ACS Publications
Cyclopropanes bearing contiguous all-carbon quaternary centers continue to attract
attention due to their bioactivities. However, methods to obtain cyclopropanes with …
attention due to their bioactivities. However, methods to obtain cyclopropanes with …
Direct observation of triplet states in the isomerization of alkenylboronates by energy transfer catalysis
Alkenylboronates are versatile building blocks for stereocontrolled synthesis owing to the
traceless nature of the boron group that can be leveraged to achieve highly selective …
traceless nature of the boron group that can be leveraged to achieve highly selective …
Metal–Organic Bichromophore Lowers the Upconversion Excitation Power Threshold and Promotes UV Photoreactions
Sensitized triplet–triplet annihilation upconversion is a promising strategy to use visible light
for chemical reactions requiring the energy input of UV photons. This strategy avoids unsafe …
for chemical reactions requiring the energy input of UV photons. This strategy avoids unsafe …
Boronic ester enabled [2+ 2]-cycloadditions by temporary coordination: synthesis of artochamin J and piperarborenine B
A strategy for the photosensitized cycloaddition of alkenylboronates and allylic alcohols by a
temporary coordination is presented. The process allows for the synthesis of a diverse range …
temporary coordination is presented. The process allows for the synthesis of a diverse range …
Electrochemical assembly of isoxazoles via a four-component domino reaction
Multicomponent domino reactions via electrochemical annulations have emerged as a
robust strategy for the rapid assembly of heterocyclics. Herein, an electrochemical …
robust strategy for the rapid assembly of heterocyclics. Herein, an electrochemical …