Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion

T Ma, R Yan, X Wu, M Wang, B Yin, S Li… - Advanced …, 2024 - Wiley Online Library
Polyoxometalates (POMs), a kind of molecular metal oxide cluster with unique physical–
chemical properties, have made essential contributions to creating efficient and robust …

Precise Assembly of Polyoxometalates at Single‐cluster Levels

Q Liu, X Wang - Angewandte Chemie, 2023 - Wiley Online Library
Polyoxometalate (POM) clusters with atomic precision structures are promising candidates
construct functional nanomaterials via self‐assembly. Non‐covalent interactions at …

Catalytically potent and selective clusterzymes for modulation of neuroinflammation through single-atom substitutions

H Liu, Y Li, S Sun, Q **n, S Liu, X Mu, X Yuan… - Nature …, 2021 - nature.com
Emerging artificial enzymes with reprogrammed and augmented catalytic activity and
substrate selectivity have long been pursued with sustained efforts. The majority of current …

Self-assembly of polyoxometalate clusters into two-dimensional clusterphene structures featuring hexagonal pores

Q Liu, Q Zhang, W Shi, H Hu, J Zhuang, X Wang - Nature Chemistry, 2022 - nature.com
Abstract Two-dimensional (2D) structures have been shown to possess interesting and
potentially useful properties. Because of their isotropic structure, however, clusters tend to …

Smart reversible transformations between chiral superstructures of copper clusters for optical and chiroptical switching

Z Han, Y Si, XY Dong, JH Hu, C Zhang… - Journal of the …, 2023 - ACS Publications
Superstructures made from nanoscale clusters with new collective properties are promising
in high-tech applications; however, chiral superstructures remain elusive, and the limited …

Constructing unique mesoporous carbon superstructures via monomicelle interface confined assembly

Z Zhao, L Duan, Y Zhao, L Wang, J Zhang… - Journal of the …, 2022 - ACS Publications
Constructing hierarchical three-dimensional (3D) mesostructures with unique pore structure,
controllable morphology, highly accessible surface area, and appealing functionality …

Polyoxometalate clusters: Sub-nanometer building blocks for construction of advanced materials

Q Liu, X Wang - Matter, 2020 - cell.com
Cluster-assembled materials based on polyoxometalates (POMs) process unprecedented
structural tunability and polymer-like behaviors because of the sub-nanometer-sized …

High-entropy-perovskite subnanowires for photoelectrocatalytic coupling of methane to acetic acid

S Nie, L Wu, Q Zhang, Y Huang, Q Liu… - Nature …, 2024 - nature.com
The incorporation of multiple immiscible metals in high-entropy oxides can create the
unconventional coordination environment of catalytic active sites, while the high formation …

Noble metal nanoparticles decorated metal oxide semiconducting nanowire arrays interwoven into 3D mesoporous superstructures for low-temperature gas sensing

Y Ren, W **e, Y Li, J Ma, J Li, Y Liu, Y Zou… - ACS central …, 2021 - ACS Publications
Mesoporous materials have been extensively studied for various applications due to their
high specific surface areas and well-interconnected uniform nanopores. Great attention has …

Hydrogen-bonded mesoporous frameworks with tunable pore sizes and architectures from nanocluster assembly units

J Zhang, LL Liu, Z Zhao, CT Hung… - Journal of the …, 2024 - ACS Publications
Construction of mesoporous frameworks by noncovalent bonding still remains a great
challenge. Here, we report a micelle-directed nanocluster modular self-assembly approach …