Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Luminescence thermometry beyond the biological realm

B Harrington, Z Ye, L Signor, AD Pickel - ACS Nanoscience Au, 2023 - ACS Publications
As the field of luminescence thermometry has matured, practical applications of
luminescence thermometry techniques have grown in both frequency and scope. Due to the …

Unique Double and Triple Decker Arrangements of Rare‐Earth 9, 10‐Diborataanthracene Complexes Featuring Single‐Molecule Magnet Characteristics

C Uhlmann, L Münzfeld, A Hauser… - Angewandte Chemie …, 2024 - Wiley Online Library
Herein, we present the first report on the synthesis of rare‐earth complexes featuring a 9, 10‐
diborataanthracene ligand. This 14‐π‐electron ligand is highly reductive and was previously …

Harnessing ligand design to develop primary and self-calibrated luminescent thermometers with field-induced single ion magnet behaviour in Dy 3+ complexes

J Corredoira-Vázquez, C González-Barreira… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Novel complexes {[Dy (LN6en)(OAc) 2](NO3)}· 2H2O (1· 2H2O) and {[Dy (LN6prop)(OAc)
2](NO3)}· CHCl3 (2· CHCl3), containing partially flexible symmetric N6 macrocycles, are …

Toward Magneto‐Optical Cryogenic Thermometers with High Sensitivity: A Magnetic Circular Dichroism Based Thermometric Approach

DA Gálico, M Murugesu - Angewandte Chemie International …, 2023 - Wiley Online Library
Remote temperature probing at the cryogenic range is of utmost importance for the
advancement of future quantum technologies. Despite the notable achievements in …

Making soluble Dy 2 single-molecule magnets red emissive through their functionalization by ruthenium–cyanido luminophores

M Liberka, S Chorazy - Chemical Communications, 2024 - pubs.rsc.org
We present an efficient strategy for obtaining red-emissive molecular nanomagnets by
exploring a heterometallic approach. We report the {[DyIII (4-pyridone) 5] 2 [RuII (CN) 2 …

Solvato-and vapochromic exchange-coupled Dy 2 single-molecule magnets achieved by attaching iron-cyanido metalloligands

M Liberka, M Zychowicz, S Chorazy - Inorganic Chemistry Frontiers, 2024 - pubs.rsc.org
Lanthanide single-molecule magnets (Ln-SMMs) have attracted scientific attention due to
their potential application in data storage and spintronics. On the other hand, stimuli …

Cobalt (II) coordination polymers with single-ion magnet property

Y Wan, YL Zhang, Q Zhang, SY Yang, D Shao - CrystEngComm, 2024 - pubs.rsc.org
Single-ion magnets (SIMs) are composed of 3d and/or 4f complexes with substantial energy
barriers that inhibit spin reversal at the molecular level. The magnetic bistability of SIMs …

Magnetic behaviour of a spin-canted asymmetric lanthanide quinolate trimer

L Batista, S Paul, C Molina-Jirón, JA Jaén… - Dalton …, 2024 - pubs.rsc.org
An asymmetrical dysprosium trimer with a molecular formula of [Dy3 (hq) 7 (hqH)(NO3) 2
(H2O)] was obtained through a reflux reaction employing as starting material Dy (NO3) 3 …

Design of Dy III single-molecule magnets with molecularly installed luminescent thermometers based on bridging [Pt II (CN) 2 (C^ N)]− complexes

PJ Bonarek, M Zychowicz, J Rzepiela… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Luminescent Single-Molecule Magnets (SMMs) have gained broad scientific attention due to
their potential applications in the dual sensing of temperature and magnetic field or optical …