Kinetic resolution of homoaldols via catalytic asymmetric transacetalization

I Coric, S Müller, B List - Journal of the American Chemical …, 2010 - ACS Publications
The highly enantioselective kinetic resolution of homoaldols via a transacetalization reaction
has been achieved. A novel phosphoric acid, STRIP, based on a spirocyclic 1, 1 …

Enantioselective construction of tertiary C–O bond via allylic substitution of vinylethylene carbonates with water and alcohols

A Khan, S Khan, I Khan, C Zhao, Y Mao… - Journal of the …, 2017 - ACS Publications
An efficient method for the enantioselective construction of tertiary C–O bond via asymmetric
allylic substitution of racemic vinylethylene carbonates with water and alcohols has been …

Palladium‐Catalyzed Decarboxylative Cycloaddition of Vinylethylene Carbonates with Formaldehyde: Enantioselective Construction of Tertiary Vinylglycols

A Khan, R Zheng, Y Kan, J Ye, J **ng… - Angewandte …, 2014 - Wiley Online Library
An efficient method for the enantioselective construction of tertiary vinylglycols through a
palladium‐catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates …

Recent advances in catalytic nonenzymatic kinetic resolution of tertiary alcohols

B Ding, Q Xue, S Jia, HG Cheng, Q Zhou - Synthesis, 2022 - thieme-connect.com
The kinetic resolution (KR) of racemates is one of the most widely used approaches to
access enantiomerically pure compounds. Over the past two decades, catalytic …

Recent advances in kinetic resolution of tertiary alcohols

C Yunrong, L Wei, Y **aoyu - Chinese Journal of Organic Chemistry, 2022 - sioc-journal.cn
Chiral tertiary alcohol is widely present in a series of bioactive compounds, natural products
and pharmaceuticals. Consequently, the development of efficient asymmetric catalytic …

Kinetic resolution of tertiary alcohols: highly enantioselective access to 3-hydroxy-3-substituted oxindoles.

S Lu, SB Poh, WY Siau, Y Zhao - Angewandte Chemie, 2013 - search.ebscohost.com
In contrast to the well-established kinetic resolution of secondary alcohols,[1] use of the
tertiary alcohol kinetic resolution has remained limited with only a handful of systems …

Organocatalytic enantioselective decarboxylative aldol reaction of malonic acid half thioesters with aldehydes.

HY Bae, JH Sim, JW Lee, B List… - Angewandte …, 2013 - search.ebscohost.com
The direct asymmetric aldol reaction is one of the most powerful and fundamental tools for
forming new carbon–carbon bonds and chiral hydroxy functional groups simultaneously.[1] …

Biomimetic catalytic enantioselective decarboxylative aldol reaction of β-ketoacids with trifluoromethyl ketones

Y Zheng, HY **ong, J Nie, MQ Hua… - Chemical Communications, 2012 - pubs.rsc.org
Biomimetic catalytic enantioselective decarboxylative aldol reaction of β-ketoacids with
trifluoromethyl ketones - Chemical Communications (RSC Publishing) DOI:10.1039/C2CC30949A …

Structure-enantioselectivity effects in 3, 4-dihydropyrimido [2, 1-b] benzothiazole-based isothioureas as enantioselective acylation catalysts

D Belmessieri, C Joannesse, PA Woods… - Organic & …, 2011 - pubs.rsc.org
The catalytic activity and enantioselectivity in the kinetic resolution of (±)-1-naphthylethanol
with a range of structurally related 3, 4-dihydropyrimido [2, 1-b] benzothiazole-based …

Construction of Chiral Bridged Tricyclic Benzopyrans: Enantioselective Catalytic Diels–Alder Reaction and a One‐Pot Reduction/Acid‐Catalyzed Stereoselective …

A Song, X Zhang, X Song, X Chen, C Yu… - Angewandte Chemie …, 2014 - Wiley Online Library
An asymmetric two‐step approach to chiral bridged tricyclic benzopyrans, core structures
featured in various natural products, is described. In the synthesis, an unprecedented …