Recent advances in the assembly of high-nuclearity lanthanide clusters

XY Zheng, J **e, XJ Kong, LS Long… - Coordination Chemistry …, 2019 - Elsevier
High-nuclearity lanthanide clusters have attracted much attention in different fields because
of their unique physical and chemical properties and their potential applications. In this …

Rare‐Earth Metal Oxo/Hydroxo Clusters–Synthesis, Structures, and Applications

AT Wagner, PW Roesky - European Journal of Inorganic …, 2016 - Wiley Online Library
Multinuclear rare‐earth metal coordination clusters bridged by oxo/hydroxo units have
emerged from being lab curiosities to become a readily accessible class of compounds …

Luminescent cell-penetrating pentadecanuclear lanthanide clusters

DT Thielemann, AT Wagner, E Rösch… - Journal of the …, 2013 - ACS Publications
A novel pentadecanuclear lanthanide hydroxy cluster [{Ln15 (μ3-OH) 20 (PepCO2) 10
(DBM) 10Cl} Cl4](Ln= Eu (1), Tb (2)) featuring the first example with peptoids as supporting …

Hydrolytic synthesis and structural characterization of lanthanide-acetylacetonato/hydroxo cluster complexes–A systematic study

Y Wu, S Morton, X Kong, GS Nichol, Z Zheng - Dalton Transactions, 2011 - pubs.rsc.org
Lanthanide hydroxide cluster complexes with acetylacetonate were synthesized by the
hydrolysis of the corresponding hydrated lanthanide acetylacetonates in methanol in the …

Variation of structural motifs in lanthanoid hydroxo clusters by ligand modification

PC Andrews, WJ Gee, PC Junk, M Massi - New Journal of Chemistry, 2013 - pubs.rsc.org
The isolation of multinuclear lanthanoid clusters with different nuclearities and geometries
commenced as a serendipitous discovery and is now the focus of intense research, not only …

New Structural Form of a Tetranuclear Lanthanide Hydroxo Cluster: Dy4 Analogue Display Slow Magnetic Relaxation

AK Jami, V Baskar, EC Sanudo - Inorganic Chemistry, 2013 - ACS Publications
A series of tetranuclear lanthanide (Ln= Tb, Dy, Ho) hydroxo clusters has been synthesized
by reaction of LnCl3· 6H2O (Ln= Tb (1), Dy (2), Ho (3)) with o-vanilin based schiff base …

Effect of coordination geometry on the magnetic properties of a series of Ln 2 and Ln 4 hydroxo clusters

A Rasamsetty, C Das, EC Sañudo… - Dalton …, 2018 - pubs.rsc.org
A series of three isostructural tetranuclear complexes with the general molecular formula
[Ln4 (μ3-OH) 4 (L) 4 (μ2-piv) 4 (MeOH) 4](Ln= Gd 1, Dy 2 and Ho 3; LH=[1, 3-bis (o …

Pentagram-type Ln 15 (Ln= Dy, Tb, Eu, Sm, Ho) clusters with different anion templates: magnetic and luminescence properties

Y Zou, W Lv, Z Xue, J Pan, XY Li, GM Wang - Dalton Transactions, 2022 - pubs.rsc.org
Five 15-nuclearity lanthanide clusters were obtained under solvothermal conditions based
on N-tris (hydroxymethyl) methylglycine (H5thmmg) with molecular formulas Ln15 (OH) 20 …

Slow magnetic relaxation in four square-based pyramidal dysprosium hydroxo clusters ligated by chiral amino acid anions–a comparative study

DT Thielemann, AT Wagner, Y Lan, CE Anson… - Dalton …, 2013 - pubs.rsc.org
The synthesis and characterization of three chiral and one achiral amino acid anion ligated
dysprosium hydroxo clusters [Dy5 (OH) 5 (α-AA) 4 (Ph2acac) 6](α-AA= D-PhGly, L-Pro, L …

Peptoid‐Ligated Pentadecanuclear Yttrium and Dysprosium Hydroxy Clusters

DT Thielemann, AT Wagner, Y Lan… - … A European Journal, 2015 - Wiley Online Library
A new family of pentadecanuclear coordination cluster compounds (from now on simply
referred to as clusters)[{Ln15 (OH) 20 (PepCO2) 10 (DBM) 10Cl} Cl4](PepCO2= 2‐[{3‐(((tert …