Enzyme-mediated oxidations for the chemist

F Hollmann, IWCE Arends, K Buehler, A Schallmey… - Green …, 2011 - pubs.rsc.org
Biocatalysis is an enabling technology adding to organic oxidation chemistry. Especially the
high selectivity of enzymatic oxidation coevally operating under mild conditions and not …

[BOOK][B] Comprehensive asymmetric catalysis: Supplement 1

EN Jacobsen, A Pfaltz, H Yamamoto - 2003 - books.google.com
The first supplement to the three volume reference work" Comprehensive Asymmetric
Catalysis" critically reviews new developments to the hottest topics in the field written by …

From a racemate to a single enantiomer: deracemization by stereoinversion

CC Gruber, I Lavandera, K Faber… - Advanced Synthesis & …, 2006 - Wiley Online Library
The stereoinversion of one enantiomer into its mirror‐image counterpart within a racemate
furnishes a single stereoisomeric product in 100% theoretical yield. This extremely efficient …

Enzyme catalysed deracemisation and dynamic kinetic resolution reactions

NJ Turner - Current opinion in chemical biology, 2004 - Elsevier
New catalysts and reaction conditions have been developed for the dynamic kinetic
resolution or deracemisation of racemic mixtures of chiral compounds. Specific functional …

Biocatalysis

G Torrelo, U Hanefeld, F Hollmann - Catalysis Letters, 2015 - Springer
Biocatalysis is an enabling technology for chemists. Using isolated enzymes or whole cells
gives access to a broad range of selective transformations—often inaccessible with …

Biocatalysed reductions of α-ketoesters employing CyreneTM as cosolvent

G de Gonzalo - Biocatalysis and Biotransformation, 2022 - Taylor & Francis
The search for novel reaction media with environmental friendly properties is an area of
great interest in enzyme catalysis. Water is the medium of biocatalysed processes, but due …

Recycling in asymmetric catalysis

C Moberg - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Cyclic reaction networks consisting of an enantioselective product-forming step
and a reverse reaction of the undesired enantiomer back to starting reactant are important …

Candida parapsilosis: A versatile biocatalyst for organic oxidation-reduction reactions

A Chadha, S Venkataraman, R Preetha, SK Padhi - Bioorganic chemistry, 2016 - Elsevier
This review highlights the importance of the biocatalyst, Candida parapsilosis for oxidation
and reduction reactions of organic compounds and establishes its versatility to generate a …

Highly enantioselective conversion of racemic 1-phenyl-1, 2-ethanediol by stereoinversion involving a novel cofactor-dependent oxidoreduction system of Candida p …

Y Nie, Y Xu, XQ Mu - Organic process research & development, 2004 - ACS Publications
An economical and convenient biocatalytic process was developed for the preparation of (S)-
1-phenyl-1, 2-ethanediol (PED), which is a valuable chiral building block for …

Efficient Reduction of Ethyl 2‐Oxo‐4‐phenylbutyrate at 620 g⋅L−1 by a Bacterial Reductase with Broad Substrate Spectrum

Y Ni, CX Li, J Zhang, ND Shen… - Advanced Synthesis …, 2011 - Wiley Online Library
A β‐ketoacyl‐ACP reductase (FabG) gene from Bacillus sp. ECU0013 was heterologously
overexpressed in Escherichia coli and the encoded protein was purified to homogeneity …