Homogeneous and heterogeneous gold catalysis for materials science

CM Hendrich, K Sekine, T Koshikawa… - Chemical …, 2020 - ACS Publications
Often stoichiometric amounts of gold find use in materials science; occasionally gold is even
used as a support. This review discusses the contributions of gold catalysis, both …

Recovery and purification of ionic liquids from solutions: a review

J Zhou, H Sui, Z Jia, Z Yang, L He, X Li - Rsc Advances, 2018 - pubs.rsc.org
With low melting point, extremely low vapor pressure and non-flammability, ionic liquids
have been attracting much attention from academic and industrial fields. Great efforts have …

Breathing new life into nonalternant hydrocarbon chemistry: Syntheses and properties of polycyclic hydrocarbons containing azulene, pentalene, and heptalene …

A Konishi, M Yasuda - Chemistry Letters, 2021 - academic.oup.com
Abstract Azulene 1, pentalene 2, and heptalene 3 are classical nonalternant hydrocarbons.
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …

Recent Progress in High Linearly Fused Polycyclic Conjugated Hydrocarbons (PCHs, n > 6) with Well‐Defined Structures

W Chen, F Yu, Q Xu, G Zhou, Q Zhang - Advanced Science, 2020 - Wiley Online Library
Although polycyclic conjugated hydrocarbons (PCHs) and their analogues have gained
great progress in the fields of organic photoelectronic materials, the in‐depth study on …

Antiaromatic Dicyclopenta[b,g]/[a,f]naphthalene Isomers Showing an Open-Shell Singlet Ground State with Tunable Diradical Character

T Xu, Y Han, Z Shen, X Hou, Q Jiang… - Journal of the …, 2021 - ACS Publications
Since the first isolation of 1, 3, 5, 7-tetra-tert-butyl-s-indacene in 1986, core-expanded s-and
as-indacenes have attracted intensive interest. However, there is no reported synthesis of …

Structure–reactivity relationships in borane-based FLP-catalyzed hydrogenations, dehydrogenations, and cycloisomerizations

J Paradies - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The activation of molecular hydrogen by main-group element catalysts is an
extremely important approach to metal-free hydrogenations. These so-called frustrated …

The Impact of Antiaromatic Subunits in [4n+2] π-Systems: Bispentalenes with [4n+2] π-Electron Perimeters and Antiaromatic Character

J Cao, G London, O Dumele… - Journal of the …, 2015 - ACS Publications
Three series of stable, neutral, π-extended bispentalene derivatives, with two pentalenes
fused to a central benzene or naphthalene moiety, have been prepared through a modified …

From structure to novel reactivity in frustrated Lewis pairs

J Paradies - Coordination Chemistry Reviews, 2019 - Elsevier
The coexistence of a strong Lewis acid and a Lewis base in solution, the so called frustrated
Lewis pair, has led to the discovery of metal-free hydrogen activation. Since then, this …

Non‐Alternant Non‐Benzenoid A romatic C ompounds: Past, Present, and Future

Y Tobe - The Chemical Record, 2015 - Wiley Online Library
The development of the chemistry of non‐alternant non‐benzenoid hydrocarbons is
reviewed in connection with the I nternational S ymposium on N ovel A romatic C ompounds …

B2N2-Dibenzo[a,e]pentalenes: Effect of the BN Orientation Pattern on Antiaromaticity and Optoelectronic Properties

XY Wang, A Narita, X Feng… - Journal of the American …, 2015 - ACS Publications
Two BN units were embedded in dibenzo [a, e] pentalene with different orientation patterns,
which significantly modulated its antiaromaticity and optoelectronic properties. Importantly …