Ultrafast elementary photochemical processes of organic molecules in liquid solution

T Kumpulainen, B Lang, A Rosspeintner… - Chemical …, 2017 - ACS Publications
Ultrafast photochemical reactions in liquids occur on similar or shorter time scales compared
to the equilibration of the optically populated excited state. This equilibration involves the …

Structural changes accompanying intramolecular electron transfer: focus on twisted intramolecular charge-transfer states and structures

ZR Grabowski, K Rotkiewicz, W Rettig - Chemical reviews, 2003 - ACS Publications
Zbigniew Ryszard Grabowski was born 1927 (original prewar name Ryszard Abrahamer).
Under the German occupation he was self-taught while in hiding. He took part in the Warsaw …

Reference energies for intramolecular charge-transfer excitations

PF Loos, M Comin, X Blase… - Journal of Chemical …, 2021 - ACS Publications
With the aim of completing our previous efforts devoted to local and Rydberg transitions in
organic compounds, we provide a series of highly accurate vertical transition energies for …

The role of hydrogen bonding in excited state intramolecular charge transfer

FAS Chipem, A Mishra… - Physical Chemistry …, 2012 - pubs.rsc.org
Intramolecular charge transfer (ICT) that occurs upon photoexcitation of molecules is a vital
process in nature and it has ample applications in chemistry and biology. The ICT process of …

Fluorescence modulation by amines: Mechanistic insights into twisted intramolecular charge transfer (TICT) and beyond

C Chen, C Fang - Chemosensors, 2023 - mdpi.com
Amine groups are common constituents of organic dyes and play important roles in tuning
fluorescence properties. In particular, intensive research works have demonstrated the …

Time-dependent density functional theory (TDDFT) study of the excited charge-transfer state formation of a series of aromatic donor− acceptor systems

C Jamorski Jödicke, HP Lüthi - Journal of the American Chemical …, 2003 - ACS Publications
Singlet excitation energy calculations for a series of acceptor para-substituted N, N-dimethyl-
anilines that are dual (4-(N, N-dimethylamino) benzonitrile, 4DMAB-CN, 4-(N, N …

Comment on “Pseudo-Jahn–Teller and TICT-models: a photophysical comparison of meta-and para-DMABN derivatives”[Chem. Phys. Lett. 305 (1999) 8]: The PICT …

KA Zachariasse - Chemical Physics Letters, 2000 - Elsevier
Due to the larger admixture of charge transfer (CT) in the intramolecular charge transfer
(ICT) state than in the locally excited (LE) state of dual fluorescent molecules such as 4 …

Dynamics of ultrafast intramolecular charge transfer with 4-(dimethylamino) benzonitrile in acetonitrile

SI Druzhinin, NP Ernsting, SA Kovalenko… - The Journal of …, 2006 - ACS Publications
The kinetics of the intramolecular charge-transfer (ICT) reaction of 4-(dimethylamino)
benzonitrile (DMABN) in the polar solvent acetonitrile (MeCN) is investigated by …

Substituent-Dependent Photoinduced Intramolecular Charge Transfer in N-Aryl-Substituted trans-4-Aminostilbenes

JS Yang, KL Liau, CM Wang… - Journal of the American …, 2004 - ACS Publications
The photochemical behavior of trans-4-(N-arylamino) stilbene (1, aryl= 4-substituted phenyl)
in solvents more polar than THF is strongly dependent on the substituent in the N-aryl group …

Intramolecular radiative and radiationless charge recombination processes in donor− acceptor carbazole derivatives

A Kapturkiewicz, J Herbich, J Karpiuk… - The Journal of Physical …, 1997 - ACS Publications
Photoinduced intramolecular charge transfer (ICT) in a series of N-bonded donor− acceptor
derivatives of 3, 6-di-tert-butylcarbazole containing benzonitrile, nicotinonitrile, or various …