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Reversed controlled polymerization (RCP): depolymerization from well-defined polymers to monomers
Controlled polymerization methods are well-established synthetic protocols for the design
and preparation of polymeric materials with a high degree of precision over molar mass and …
and preparation of polymeric materials with a high degree of precision over molar mass and …
Ultrasonics in polymer science: applications and challenges
Ultrasonic waves in a liquid media generate both chemical and mechanistic effects that are
actively used to perform chemical reactions, polymer synthesis, nanoparticle synthesis …
actively used to perform chemical reactions, polymer synthesis, nanoparticle synthesis …
Photocatalytic ATRP depolymerization: temporal control at low ppm of catalyst concentration
A photocatalytic ATRP depolymerization is introduced that significantly suppresses the
reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis
C Rao, T Zhang, H Liu, H Huang - Nature Catalysis, 2023 - nature.com
Selective construction of two distinct alkyl–alkyl bonds across the C= C bond of simple
unactivated olefins is a persistent challenge in organic synthesis. Transition metal-catalysed …
unactivated olefins is a persistent challenge in organic synthesis. Transition metal-catalysed …
Fast bulk depolymerization of polymethacrylates by ATRP
Fast bulk depolymerization of poly (n-butyl methacrylate) and poly (methyl methacrylate),
prepared by atom transfer radical polymerization (ATRP), is reported in the temperature …
prepared by atom transfer radical polymerization (ATRP), is reported in the temperature …
Red-light-driven atom transfer radical polymerization for high-throughput polymer synthesis in open air
Photoinduced reversible-deactivation radical polymerization (photo-RDRP) techniques offer
exceptional control over polymerization, providing access to well-defined polymers and …
exceptional control over polymerization, providing access to well-defined polymers and …
Open-air green-light-driven ATRP enabled by dual photoredox/copper catalysis
Photoinduced atom transfer radical polymerization (photo-ATRP) has risen to the forefront of
modern polymer chemistry as a powerful tool giving access to well-defined materials with …
modern polymer chemistry as a powerful tool giving access to well-defined materials with …
Light-accelerated depolymerization catalyzed by Eosin Y
Retrieving the starting monomers from polymers synthesized by reversible deactivation
radical polymerization has recently emerged as an efficient way to increase the recyclability …
radical polymerization has recently emerged as an efficient way to increase the recyclability …
Solvent‐Free Chemical Recycling of Polymethacrylates made by ATRP and RAFT polymerization: High‐Yielding Depolymerization at Low Temperatures
Although controlled radical polymerization is an excellent tool to make precision polymeric
materials, reversal of the process to retrieve the starting monomer is far less explored …
materials, reversal of the process to retrieve the starting monomer is far less explored …
Depolymerization of polymethacrylates by iron ATRP
Recycling of polymers has become increasingly relevant with the focus on a circular
economy. Controlled radical polymerizations create an avenue for polymerization and …
economy. Controlled radical polymerizations create an avenue for polymerization and …