Magnetic materials based on heterometallic Cr II/III–Ln III complexes

P Shukla, S Das, P Bag, A Dey - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Accommodating disparate spin centres within a single ensemble is a valuable synthetic
strategy to obtain interesting molecular magnetic materials. 3d–4f heterometallic complexes …

Lanthanide SMMs based on belt macrocycles: Recent advances and general trends

Y Gil, A Castro‐Alvarez, P Fuentealba… - … A European Journal, 2022 - Wiley Online Library
Enhancement of axial magnetic anisotropy is the central objective to push forward the
performance of Single‐Molecule Magnet (SMM) complexes. In the case of mononuclear …

A hundredfold enhancement of relaxation times among Er (iii) single-molecule magnets with comparable energy barriers

QW Chen, YS Ding, T Xue, XF Zhu… - Inorganic Chemistry …, 2023 - pubs.rsc.org
Magneto-structural correlations are of great importance in develo** single-molecule
magnets (SMMs) for storage and quantum processing of information. In this work, three …

Rare earth ion doped luminescent materials: a review of up/down conversion luminescent mechanism, synthesis, and anti-counterfeiting application

Z Chen, H Zhu, J Qian, Z Li, X Hu, Y Guo, Y Fu, H Zhu… - Photonics, 2023 - mdpi.com
With the rapid development of modern technology and information systems, optical anti-
counterfeiting and encryption have recently attracted considerable attention. The demand for …

Blue-Emitting Ligand-Mediated Assembly of Rare-Earth MOFs toward White-Light Emission, Sensing, Magnetic, and Catalytic Studies

K Manna, JP Sutter, S Natarajan - Inorganic Chemistry, 2022 - ACS Publications
New lanthanide carboxylate compounds with two-(2D) and three-dimensional (3D)
structures have been prepared by employing 2, 5-bis (prop-2-yn-1-yloxy) terephthalic acid …

Slow magnetic relaxation in a homoaxially phosphine oxide coordinated pentagonal bipyramidal Dy (III) complex

P Kalita, N Ahmed, S Moorthy, V Béreau, AK Bar… - Dalton …, 2023 - pubs.rsc.org
We report the synthesis of [(L) DyIII (Cy3PO) 2]·[BPh4](1-Dy)(where H2L= 2, 6-
diacetylpyridine bis-benzoylhydrazone and Cy= cyclohexyl) which crystallized in the triclinic …

Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co {(OPPh 2)(EPPh 2) N} 2], E= S, Se, explored by experimental and …

E Ferentinos, D Tzeli, S Sottini, EJJ Groenen… - Dalton …, 2023 - pubs.rsc.org
During the last few years, a large number of mononuclear Co (II) complexes of various
coordination geometries have been explored as potential single ion magnets (SIMs). In the …

Spectroscopic techniques to probe magnetic anisotropy and spin–phonon coupling in metal complexes

AT Hand, BD Watson-Sanders, ZL Xue - Dalton Transactions, 2024 - pubs.rsc.org
Magnetism of molecular quantum materials such as single-molecule magnets (SMMs) has
been actively studied for potential applications in the new generation of high-density data …

Single-Molecule Magnet Behavior in a Tb-Nitronyl Nitroxide Radical Network with [Tb3(NIT)2] Nodes

CY **, XL Mei, Y Zhou, L Li, JP Sutter - Inorganic Chemistry, 2024 - ACS Publications
Two rare two-dimensional Ln-radical networks, namely,[{Ln (tfa) 3} 3 (NIT-4Py) 2] n [LnIII=
Gd 1 and Tb 2; tfa–= trifluoroacetylacetonato; and NIT-4Py= 2-(4-pyridyl)-4, 4, 5, 5 …

Multiconfiguration Pair-Density Functional Theory for Chromium (IV) Molecular Qubits

A Sauza-De La Vega, R Pandharkar, GD Stroscio… - JACS Au, 2022 - ACS Publications
Pseudotetrahedral organometallic complexes containing chromium (IV) and aryl ligands
have been experimentally identified as promising molecular qubit candidates. Here we …