Recent advances in catalytic carbonylation reactions in alternative reaction media

C Árvai, LT Mika - Chinese Journal of Chemistry, 2024 - Wiley Online Library
Comprehensive Summary Since the discovery of the hydroformylation (oxo‐synthesis or
Roelen reaction) and the Reppe‐reaction, the transition metal‐catalyzed carbonylation …

Exploration of New Biomass‐Derived Solvents: Application to Carboxylation Reactions

A Gevorgyan, KH Hopmann, A Bayer - ChemSusChem, 2020 - Wiley Online Library
A range of hitherto unexplored biomass‐derived chemicals have been evaluated as new
sustainable solvents for a large variety of CO2‐based carboxylation reactions. Known …

Polydopamine‐Encapsulated Dendritic Organosilica Nanoparticles as Amphiphilic Platforms for Highly Efficient Heterogeneous Catalysis in Water

Y Liu, Z Wang, N Guo, P Liu, G Liu… - Chinese Journal of …, 2021 - Wiley Online Library
Main observation and conclusion Aqueous heterogeneous catalysis is a green, sustainable
catalytic process that attracts increasing attention, but it often suffers from poor mass transfer …

Recent Advancements in Continuous‐Flow Suzuki‐Miyaura Coupling Utilizing Immobilized Molecular Palladium Complexes

Z Zhang, YMA Yamada - Chemistry–A European Journal, 2024 - Wiley Online Library
Abstract Immobilized Pd‐catalyzed Suzuki‐Miyaura coupling under continuous‐flow
conditions using a packed‐bed reactor, representing an efficient, automated, practical, and …

Electrode Development for Electro‐Organic Kolbe–Schmitt C–H Carboxylation of Benzene Using Cu Nanoparticles on Graphene Oxide Modified With MIL‐101 MOF …

Z Behrouz, K Banihashemi, M Saadat… - Applied …, 2025 - Wiley Online Library
This study focuses on develo** an advanced electrode for the electro‐organic Kolbe–
Schmitt C–H carboxylation of benzene. The electrode uses copper (Cu) nanoparticles …

Supported Bis-(NHC)-P (II) Complex: A phosphine-Free Catalyst Supported on Magnetic Mesoporous Silica for The CO-Free Carbonylation of Aryl Halides

S Fekri, Y Mansoori - Journal of Organometallic Chemistry, 2024 - Elsevier
In this work, our previously reported bis (NHC)-Pd (II) catalyst grafted on Fe 3 O 4@ SBA-15
has been successfully used as a phosphine-free heterogeneous magnetic catalyst in the CO …

Palladium-Catalyzed Ligand-Free ortho-Deuteration of Aromatic Carboxylic Acids with D2O

Z Zhang, ZJ Jiang, Y Cao, J Chen, Z Gao - Synthesis, 2022 - thieme-connect.com
A ligand-free, palladium-catalyzed ortho-deuteration of aromatic carboxylic acids was
developed using D 2 O as the deuterium source. Compared to their meta-substituted …

Amphiphilic immobilized diphenylprolinol alkyl ether catalyst on PS-PEG resin

S Koshino, S Hattori, S Hasegawa… - Bulletin of the …, 2021 - academic.oup.com
Diphenylprolinol silyl ether is a widely used organocatalyst, and its immobilization on a solid
support was investigated for the easy recycling and reuse of this catalyst. Because a silyl …

Metal‐Free Photooxidation of Toluene Derivatives into the Corresponding Carboxylic Acids and Aldehydes by a HBr/NaOCl·5H2O System

M Kirihara, T Kawai, A Kitajima, S Yamahara… - …, 2024 - Wiley Online Library
Photobromination of toluene derivatives using blue LED (454 nm) or UV LEDs (365, 385,
395 nm) with aqueous HBr and NaOCl· 5H2O in trifluoromethyl benzene afforded the …

Palladium‐Catalyzed Aminocarbonylation of Aryl Halides with N,N‐Dialkylformamide Acetals

S Hirata, T Osako, Y Uozumi - Helvetica Chimica Acta, 2021 - Wiley Online Library
We developed a protocol for the palladium‐catalyzed aminocarbonylation of aryl halides
using less‐toxic formamide acetals as bench‐stable aminocarbonyl sources under neutral …