In recent years, remarkable progress has been described in the development of methods
that simultaneously control vicinal stereochemistry, wherein both stereochemical elements …

Herein, we report a photoredox/copper dual-catalyzed selective phosphorothiolation of
propargylic derivatives from easily accessible [P (O) SH] compounds. This reaction provides …

Axially chiral allenes bearing organoboron groups are highly sought-after building blocks in
organic synthesis due to their potential for generating a wide range of axially and centrally …

In recent decades transition metals have made a substantial contribution to the development
of novel synthetic processes, with palladium catalysis being, arguably, at the forefront of this …

Herein, a highly regioselective alkylation of propargylic carbonates for trisubstituted allenes
with alkyl 1, 4-dihydropyridine derivatives (1, 4-DHPs) is developed via a photoredox/nickel …

Herein, a highly regioselective alkylation of propargylic carbonates for trisubstituted allenes
with alkyl N-hydroxyphthalimide (NHP) esters was developed via a nickel-mediated radical …

Herein, we report the first allenylic alkylation with bench-stable aliphatic amine-derived
Katritzky salts via photoredox/nickel dual-catalyzed reductive deaminative cross-electrophile …

We report a practical in situ quench (ISQ) procedure involving the generation of chiral
secondary alkyllithiums from secondary alkyl iodides (including functionalized iodides …

A general preparation of enantiomerically and diastereomerically enriched secondary
alkylmagnesium reagents was reported as well as their use for performing highly …

Rh (I)‐catalyzed decarboxylative arylation of alkynyl cyclic carbonates using commercially
available and low‐toxic aryl boronic acids has been disclosed. Depending on the nature of …