Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022 - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Visible light-responsive materials: the (photo) chemistry and applications of donor–acceptor Stenhouse adducts in polymer science

M Clerc, S Sandlass, O Rifaie-Graham… - Chemical Society …, 2023 - pubs.rsc.org
Donor–acceptor Stenhouse adduct (DASA) photoswitches have gained a lot of attention
since their discovery in 2014. Their negative photochromism, visible light absorbance …

Multiple yet controllable photoswitching in a single AIEgen system

P Wei, JX Zhang, Z Zhao, Y Chen, X He… - Journal of the …, 2018 - ACS Publications
Seeking new methods to obtain elaborate artificial on-demand photoswitching with multiple
functionalities remains challenging. Most of the systems reported so far possess only one …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

A multi-stage single photochrome system for controlled photoswitching responses

F Stricker, DM Sanchez, U Raucci, ND Dolinski… - Nature Chemistry, 2022 - nature.com
The ability of molecular photoswitches to convert on/off responses into large macroscale
property change is fundamental to light-responsive materials. However, moving beyond …

Photoswitchable gating of non-equilibrium enzymatic feedback in chemically communicating polymersome nanoreactors

O Rifaie-Graham, J Yeow, A Najer, R Wang, R Sun… - Nature Chemistry, 2023 - nature.com
The circadian rhythm generates out-of-equilibrium metabolite oscillations that are controlled
by feedback loops under light/dark cycles. Here we describe a non-equilibrium nanosystem …

Wavelength-selective light-responsive DASA-functionalized polymersome nanoreactors

O Rifaie-Graham, S Ulrich… - Journal of the …, 2018 - ACS Publications
Transient activation of biochemical reactions by visible light and subsequent return to the
inactive state in the absence of light is an essential feature of the biochemical processes in …

Solution mask liquid lithography (SMaLL) for one‐step, multimaterial 3D printing

ND Dolinski, ZA Page, EB Callaway… - Advanced …, 2018 - Wiley Online Library
A novel methodology for printing 3D objects with spatially resolved mechanical and
chemical properties is reported. Photochromic molecules are used to control polymerization …

Photocontrolled living polymerization systems with reversible deactivations through electron and energy transfer

S Shanmugam, J Xu, C Boyer - Macromolecular Rapid …, 2017 - Wiley Online Library
Recently, visible‐light‐regulated polymerization has been gaining popularity, as it opens a
range of new opportunities for the synthesis of functional polymers and materials. Here, the …

Sample illumination device facilitates in situ light-coupled NMR spectroscopy without fibre optics

JE Bramham, AP Golovanov - Communications Chemistry, 2022 - nature.com
In situ illumination of liquid-state nuclear magnetic resonance (NMR) samples makes it
possible for a wide range of light-dependent chemical and biological phenomena to be …