As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-
titanium clusters (PTCs) have been closely related to many photo-activities that broadly …

Conspectus Atomically precise titanium-oxo clusters (TOCs) are the structure and reactivity
model compounds of technically important TiO2 materials, which could help build structure …

While the difference in catalytic reactivity between mono-and multimetallic sites is often
attributed to more than just the number of active sites, still few catalyst model systems have …

The Lewis acidic sites and reducing power of a photocatalyst are critical for its performance
in CO2 activation for cycloadditions. In this study, we designed and synthesized a …

Abstract Titanium (IV)‐based metal‐organic frameworks (Ti‐MOFs) have received significant
attention in recent years due to their numerous photocatalytic applications. We herein …

Group (IV) metal oxo clusters are a diverse class of compounds with rapidly growing
applications in catalysis, materials chemistry, electronics and optics. They possess unique …

Abstract A protein‐sized (ca. 4.2× 4.2× 3.6 nm3) non‐biologically derived molecule
{Nb288O768 (OH) 48 (CO3) 12}(Nb288) containing up to 288 niobium atoms has been …

Phase isomerism is a common and important phenomenon in inorganic materials, but the
molecular isomerism of their nanocluster models is still rare. In this work, we report the first …

Titanium (IV)-based metal-organic frameworks (Ti-MOFs) have received significant attention
in recent years because of their numerous photocatalytic applications; however, the …

An organic–inorganic hybrid electrolyte based on a cyclic Ti‐oxo cluster as the inorganic
core and naphthalene‐based organic ammonium bromide salts as the electrolyte was …